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Poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) N:N′)tetra­kis­(seleno­cyanato-κN)dimanganese(II)] 1,2-di-4-pyridyl­ethyl­ene disolvate]

The crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2)}(2n), consists of two crystallographically independent Mn cations, four seleno­cyanate anions, four 1,2-di-pyridylethylene (bpe) ligands (two of which are located on centers of inversion) and two bpe solven...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120600/
https://www.ncbi.nlm.nih.gov/pubmed/21754598
http://dx.doi.org/10.1107/S1600536811016199
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author Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description The crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2)}(2n), consists of two crystallographically independent Mn cations, four seleno­cyanate anions, four 1,2-di-pyridylethylene (bpe) ligands (two of which are located on centers of inversion) and two bpe solvent molecules. Each manganese(II) cation is coordinated by two terminally N-bonded seleno­cyanate anions and four bpe ligands within a slightly distorted octa­hedron. The manganese(II) cations are linked by the bpe ligands into chains that are further connected by these ligands into layers. These layers are stacked, forming cavities in which additional bpe solvent molecules are embedded.
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spelling pubmed-31206002011-07-13 Poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) N:N′)tetra­kis­(seleno­cyanato-κN)dimanganese(II)] 1,2-di-4-pyridyl­ethyl­ene disolvate] Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2)}(2n), consists of two crystallographically independent Mn cations, four seleno­cyanate anions, four 1,2-di-pyridylethylene (bpe) ligands (two of which are located on centers of inversion) and two bpe solvent molecules. Each manganese(II) cation is coordinated by two terminally N-bonded seleno­cyanate anions and four bpe ligands within a slightly distorted octa­hedron. The manganese(II) cations are linked by the bpe ligands into chains that are further connected by these ligands into layers. These layers are stacked, forming cavities in which additional bpe solvent molecules are embedded. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120600/ /pubmed/21754598 http://dx.doi.org/10.1107/S1600536811016199 Text en © Wöhlert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Jess, Inke
Näther, Christian
Poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) N:N′)tetra­kis­(seleno­cyanato-κN)dimanganese(II)] 1,2-di-4-pyridyl­ethyl­ene disolvate]
title Poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) N:N′)tetra­kis­(seleno­cyanato-κN)dimanganese(II)] 1,2-di-4-pyridyl­ethyl­ene disolvate]
title_full Poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) N:N′)tetra­kis­(seleno­cyanato-κN)dimanganese(II)] 1,2-di-4-pyridyl­ethyl­ene disolvate]
title_fullStr Poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) N:N′)tetra­kis­(seleno­cyanato-κN)dimanganese(II)] 1,2-di-4-pyridyl­ethyl­ene disolvate]
title_full_unstemmed Poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) N:N′)tetra­kis­(seleno­cyanato-κN)dimanganese(II)] 1,2-di-4-pyridyl­ethyl­ene disolvate]
title_short Poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) N:N′)tetra­kis­(seleno­cyanato-κN)dimanganese(II)] 1,2-di-4-pyridyl­ethyl­ene disolvate]
title_sort poly[[tetra­kis­(μ-1,2-di-4-pyridyl­ethyl­ene-κ(2) n:n′)tetra­kis­(seleno­cyanato-κn)dimanganese(ii)] 1,2-di-4-pyridyl­ethyl­ene disolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120600/
https://www.ncbi.nlm.nih.gov/pubmed/21754598
http://dx.doi.org/10.1107/S1600536811016199
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