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Poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2) N:N′)tetrakis(selenocyanato-κN)dimanganese(II)] 1,2-di-4-pyridylethylene disolvate]
The crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2)}(2n), consists of two crystallographically independent Mn cations, four selenocyanate anions, four 1,2-di-pyridylethylene (bpe) ligands (two of which are located on centers of inversion) and two bpe solven...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120600/ https://www.ncbi.nlm.nih.gov/pubmed/21754598 http://dx.doi.org/10.1107/S1600536811016199 |
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author | Wöhlert, Susanne Jess, Inke Näther, Christian |
author_facet | Wöhlert, Susanne Jess, Inke Näther, Christian |
author_sort | Wöhlert, Susanne |
collection | PubMed |
description | The crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2)}(2n), consists of two crystallographically independent Mn cations, four selenocyanate anions, four 1,2-di-pyridylethylene (bpe) ligands (two of which are located on centers of inversion) and two bpe solvent molecules. Each manganese(II) cation is coordinated by two terminally N-bonded selenocyanate anions and four bpe ligands within a slightly distorted octahedron. The manganese(II) cations are linked by the bpe ligands into chains that are further connected by these ligands into layers. These layers are stacked, forming cavities in which additional bpe solvent molecules are embedded. |
format | Online Article Text |
id | pubmed-3120600 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31206002011-07-13 Poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2) N:N′)tetrakis(selenocyanato-κN)dimanganese(II)] 1,2-di-4-pyridylethylene disolvate] Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2)}(2n), consists of two crystallographically independent Mn cations, four selenocyanate anions, four 1,2-di-pyridylethylene (bpe) ligands (two of which are located on centers of inversion) and two bpe solvent molecules. Each manganese(II) cation is coordinated by two terminally N-bonded selenocyanate anions and four bpe ligands within a slightly distorted octahedron. The manganese(II) cations are linked by the bpe ligands into chains that are further connected by these ligands into layers. These layers are stacked, forming cavities in which additional bpe solvent molecules are embedded. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120600/ /pubmed/21754598 http://dx.doi.org/10.1107/S1600536811016199 Text en © Wöhlert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wöhlert, Susanne Jess, Inke Näther, Christian Poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2) N:N′)tetrakis(selenocyanato-κN)dimanganese(II)] 1,2-di-4-pyridylethylene disolvate] |
title | Poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2)
N:N′)tetrakis(selenocyanato-κN)dimanganese(II)] 1,2-di-4-pyridylethylene disolvate] |
title_full | Poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2)
N:N′)tetrakis(selenocyanato-κN)dimanganese(II)] 1,2-di-4-pyridylethylene disolvate] |
title_fullStr | Poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2)
N:N′)tetrakis(selenocyanato-κN)dimanganese(II)] 1,2-di-4-pyridylethylene disolvate] |
title_full_unstemmed | Poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2)
N:N′)tetrakis(selenocyanato-κN)dimanganese(II)] 1,2-di-4-pyridylethylene disolvate] |
title_short | Poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2)
N:N′)tetrakis(selenocyanato-κN)dimanganese(II)] 1,2-di-4-pyridylethylene disolvate] |
title_sort | poly[[tetrakis(μ-1,2-di-4-pyridylethylene-κ(2)
n:n′)tetrakis(selenocyanato-κn)dimanganese(ii)] 1,2-di-4-pyridylethylene disolvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120600/ https://www.ncbi.nlm.nih.gov/pubmed/21754598 http://dx.doi.org/10.1107/S1600536811016199 |
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