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S,S′-(Pyridazine-3,6-diyl)dithiouronium dichloride methanol monosolvate
In the title compound, C(6)H(10)N(6)S(2) (2+)·2Cl(−)·CH(3)OH, the pyridazine ring is almost planar, the greatest deviation from the mean plane being 0.025 (2) Å for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87 (6) and 57.94 (7)°. The thiouronium ca...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120605/ https://www.ncbi.nlm.nih.gov/pubmed/21754846 http://dx.doi.org/10.1107/S1600536811018514 |
| Sumario: | In the title compound, C(6)H(10)N(6)S(2) (2+)·2Cl(−)·CH(3)OH, the pyridazine ring is almost planar, the greatest deviation from the mean plane being 0.025 (2) Å for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87 (6) and 57.94 (7)°. The thiouronium cations and the chloride anions are linked by strong N—H⋯Cl hydrogen bonds. The methanol solvent molecule interacts with both the chloride ion (through an O—H⋯Cl hydrogen bond) and the cation (through an N—H⋯O hydrogen bond), resulting in a three-dimensional supramolecular arrangement. |
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