S,S′-(Pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate

In the title compound, C(6)H(10)N(6)S(2) (2+)·2Cl(−)·CH(3)OH, the pyrid­azine ring is almost planar, the greatest deviation from the mean plane being 0.025 (2) Å for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87 (6) and 57.94 (7)°. The thiouronium ca...

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Autores principales: Hübscher, Jörg, Izotova, Lidiya, Talipov, Samat, Katzsch, Felix, Weber, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120605/
https://www.ncbi.nlm.nih.gov/pubmed/21754846
http://dx.doi.org/10.1107/S1600536811018514
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author Hübscher, Jörg
Izotova, Lidiya
Talipov, Samat
Katzsch, Felix
Weber, Edwin
author_facet Hübscher, Jörg
Izotova, Lidiya
Talipov, Samat
Katzsch, Felix
Weber, Edwin
author_sort Hübscher, Jörg
collection PubMed
description In the title compound, C(6)H(10)N(6)S(2) (2+)·2Cl(−)·CH(3)OH, the pyrid­azine ring is almost planar, the greatest deviation from the mean plane being 0.025 (2) Å for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87 (6) and 57.94 (7)°. The thiouronium cations and the chloride anions are linked by strong N—H⋯Cl hydrogen bonds. The methanol solvent mol­ecule inter­acts with both the chloride ion (through an O—H⋯Cl hydrogen bond) and the cation (through an N—H⋯O hydrogen bond), resulting in a three-dimensional supra­molecular arrangement.
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spelling pubmed-31206052011-07-13 S,S′-(Pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate Hübscher, Jörg Izotova, Lidiya Talipov, Samat Katzsch, Felix Weber, Edwin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(10)N(6)S(2) (2+)·2Cl(−)·CH(3)OH, the pyrid­azine ring is almost planar, the greatest deviation from the mean plane being 0.025 (2) Å for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87 (6) and 57.94 (7)°. The thiouronium cations and the chloride anions are linked by strong N—H⋯Cl hydrogen bonds. The methanol solvent mol­ecule inter­acts with both the chloride ion (through an O—H⋯Cl hydrogen bond) and the cation (through an N—H⋯O hydrogen bond), resulting in a three-dimensional supra­molecular arrangement. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120605/ /pubmed/21754846 http://dx.doi.org/10.1107/S1600536811018514 Text en © Hübscher et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hübscher, Jörg
Izotova, Lidiya
Talipov, Samat
Katzsch, Felix
Weber, Edwin
S,S′-(Pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate
title S,S′-(Pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate
title_full S,S′-(Pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate
title_fullStr S,S′-(Pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate
title_full_unstemmed S,S′-(Pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate
title_short S,S′-(Pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate
title_sort s,s′-(pyridazine-3,6-di­yl)dithio­uronium dichloride methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120605/
https://www.ncbi.nlm.nih.gov/pubmed/21754846
http://dx.doi.org/10.1107/S1600536811018514
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