2-Amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate

In the crystal structure of the title compound, C(5)H(6)N(3)O(2) (+)·H(2)PO(4) (−), the dihydrogen phosphate anions are linked through short O—H⋯O hydrogen bonds, forming infinite double chains running parallel to the b axis. Centrosymetric N—H⋯O hydrogen-bonded cationic dimers form bridges between...

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Detalles Bibliográficos
Autores principales: Berrah, Fadila, Bouacida, Sofiane, Roisnel, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120607/
https://www.ncbi.nlm.nih.gov/pubmed/21754792
http://dx.doi.org/10.1107/S1600536811017521
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author Berrah, Fadila
Bouacida, Sofiane
Roisnel, Thierry
author_facet Berrah, Fadila
Bouacida, Sofiane
Roisnel, Thierry
author_sort Berrah, Fadila
collection PubMed
description In the crystal structure of the title compound, C(5)H(6)N(3)O(2) (+)·H(2)PO(4) (−), the dihydrogen phosphate anions are linked through short O—H⋯O hydrogen bonds, forming infinite double chains running parallel to the b axis. Centrosymetric N—H⋯O hydrogen-bonded cationic dimers form bridges between these chains by means of inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, leading to a two-dimensional network parallel to (100) in which R (3) (3)(12), R (4) (3)(10) R (2) (2)(8) and C(4) graph-set motifs are generated. Weak inter­molecular C—H⋯O hydrogen bonds connect these layers, forming a three-dimensional network.
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spelling pubmed-31206072011-07-13 2-Amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate Berrah, Fadila Bouacida, Sofiane Roisnel, Thierry Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(5)H(6)N(3)O(2) (+)·H(2)PO(4) (−), the dihydrogen phosphate anions are linked through short O—H⋯O hydrogen bonds, forming infinite double chains running parallel to the b axis. Centrosymetric N—H⋯O hydrogen-bonded cationic dimers form bridges between these chains by means of inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, leading to a two-dimensional network parallel to (100) in which R (3) (3)(12), R (4) (3)(10) R (2) (2)(8) and C(4) graph-set motifs are generated. Weak inter­molecular C—H⋯O hydrogen bonds connect these layers, forming a three-dimensional network. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120607/ /pubmed/21754792 http://dx.doi.org/10.1107/S1600536811017521 Text en © Berrah et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Berrah, Fadila
Bouacida, Sofiane
Roisnel, Thierry
2-Amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate
title 2-Amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate
title_full 2-Amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate
title_fullStr 2-Amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate
title_full_unstemmed 2-Amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate
title_short 2-Amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate
title_sort 2-amino-3-carb­oxy­pyrazin-1-ium dihydrogen phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120607/
https://www.ncbi.nlm.nih.gov/pubmed/21754792
http://dx.doi.org/10.1107/S1600536811017521
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AT bouacidasofiane 2amino3carboxypyrazin1iumdihydrogenphosphate
AT roisnelthierry 2amino3carboxypyrazin1iumdihydrogenphosphate

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