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Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))zinc trihydrate
In the crystal structure of the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Zn(II) ion, located an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. T...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120609/ https://www.ncbi.nlm.nih.gov/pubmed/21754616 http://dx.doi.org/10.1107/S160053681101676X |
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author | Zhang, Gang |
author_facet | Zhang, Gang |
author_sort | Zhang, Gang |
collection | PubMed |
description | In the crystal structure of the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Zn(II) ion, located an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. The carboxy group links with the carboxylate group of the same ligand via an intramolecular O—H⋯O hydrogen bond. An extensive intermolecular N—H⋯O and O—H⋯O hydrogen-bonded network exists in the crystal structure. One disordered lattice water molecule is half-occupied and is located close to an inversion center. |
format | Online Article Text |
id | pubmed-3120609 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31206092011-07-13 Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))zinc trihydrate Zhang, Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Zn(II) ion, located an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. The carboxy group links with the carboxylate group of the same ligand via an intramolecular O—H⋯O hydrogen bond. An extensive intermolecular N—H⋯O and O—H⋯O hydrogen-bonded network exists in the crystal structure. One disordered lattice water molecule is half-occupied and is located close to an inversion center. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120609/ /pubmed/21754616 http://dx.doi.org/10.1107/S160053681101676X Text en © Gang Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Gang Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))zinc trihydrate |
title | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc trihydrate |
title_full | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc trihydrate |
title_fullStr | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc trihydrate |
title_full_unstemmed | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc trihydrate |
title_short | Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc trihydrate |
title_sort | diaquabis(5-carboxy-2-ethyl-1h-imidazole-5-carboxylato-κ(2)
n
(3),o
(4))zinc trihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120609/ https://www.ncbi.nlm.nih.gov/pubmed/21754616 http://dx.doi.org/10.1107/S160053681101676X |
work_keys_str_mv | AT zhanggang diaquabis5carboxy2ethyl1himidazole5carboxylatok2n3o4zinctrihydrate |