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Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc trihydrate

In the crystal structure of the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Zn(II) ion, located an inversion center, is N,O-chelated by two 5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ate anions and further coordinated by two water mol­ecules in a distorted octa­hedral geometry. T...

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Detalles Bibliográficos
Autor principal: Zhang, Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120609/
https://www.ncbi.nlm.nih.gov/pubmed/21754616
http://dx.doi.org/10.1107/S160053681101676X
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author Zhang, Gang
author_facet Zhang, Gang
author_sort Zhang, Gang
collection PubMed
description In the crystal structure of the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Zn(II) ion, located an inversion center, is N,O-chelated by two 5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ate anions and further coordinated by two water mol­ecules in a distorted octa­hedral geometry. The carb­oxy group links with the carboxyl­ate group of the same ligand via an intra­molecular O—H⋯O hydrogen bond. An extensive inter­molecular N—H⋯O and O—H⋯O hydrogen-bonded network exists in the crystal structure. One disordered lattice water mol­ecule is half-occupied and is located close to an inversion center.
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spelling pubmed-31206092011-07-13 Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc trihydrate Zhang, Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·3H(2)O, the Zn(II) ion, located an inversion center, is N,O-chelated by two 5-carb­oxy-2-ethyl-1H-imidazole-4-carboxyl­ate anions and further coordinated by two water mol­ecules in a distorted octa­hedral geometry. The carb­oxy group links with the carboxyl­ate group of the same ligand via an intra­molecular O—H⋯O hydrogen bond. An extensive inter­molecular N—H⋯O and O—H⋯O hydrogen-bonded network exists in the crystal structure. One disordered lattice water mol­ecule is half-occupied and is located close to an inversion center. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120609/ /pubmed/21754616 http://dx.doi.org/10.1107/S160053681101676X Text en © Gang Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Gang
Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc trihydrate
title Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc trihydrate
title_full Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc trihydrate
title_fullStr Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc trihydrate
title_full_unstemmed Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc trihydrate
title_short Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc trihydrate
title_sort diaqua­bis­(5-carb­oxy-2-ethyl-1h-imidazole-5-carboxyl­ato-κ(2) n (3),o (4))zinc trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120609/
https://www.ncbi.nlm.nih.gov/pubmed/21754616
http://dx.doi.org/10.1107/S160053681101676X
work_keys_str_mv AT zhanggang diaquabis5carboxy2ethyl1himidazole5carboxylatok2n3o4zinctrihydrate