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[μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2) N,C (2):κ(2) C (2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2) O,O′)palladium(II)](Pd—Pd)
The title compound, [Pd(2)(C(13)H(8)N(2)O(2))(C(15)H(11)O(2))(2)], crystallized from a mixture of ethanol and n-hexanes. The structure is the first example of β-diketonate in a dianionic κ(2) C-coordination complex containing a Pd(II)—Pd(II) bond. Both Pd(II) atoms adopt a pseudo square-planar coor...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120612/ https://www.ncbi.nlm.nih.gov/pubmed/21754640 http://dx.doi.org/10.1107/S1600536811017144 |
| _version_ | 1782206718364614656 |
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| author | Maggini, Simona White, Peter S. |
| author_facet | Maggini, Simona White, Peter S. |
| author_sort | Maggini, Simona |
| collection | PubMed |
| description | The title compound, [Pd(2)(C(13)H(8)N(2)O(2))(C(15)H(11)O(2))(2)], crystallized from a mixture of ethanol and n-hexanes. The structure is the first example of β-diketonate in a dianionic κ(2) C-coordination complex containing a Pd(II)—Pd(II) bond. Both Pd(II) atoms adopt a pseudo square-planar coordination geometry. The molecular packing involves π-interactions between the phenyl rings of the 1,3-diphenylpropane-1,3-dionato ligands with centroid–centroid distances in the range 3.823 (2)–3.868 (2) Å. |
| format | Online Article Text |
| id | pubmed-3120612 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31206122011-07-13 [μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2) N,C (2):κ(2) C (2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2) O,O′)palladium(II)](Pd—Pd) Maggini, Simona White, Peter S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2)(C(13)H(8)N(2)O(2))(C(15)H(11)O(2))(2)], crystallized from a mixture of ethanol and n-hexanes. The structure is the first example of β-diketonate in a dianionic κ(2) C-coordination complex containing a Pd(II)—Pd(II) bond. Both Pd(II) atoms adopt a pseudo square-planar coordination geometry. The molecular packing involves π-interactions between the phenyl rings of the 1,3-diphenylpropane-1,3-dionato ligands with centroid–centroid distances in the range 3.823 (2)–3.868 (2) Å. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120612/ /pubmed/21754640 http://dx.doi.org/10.1107/S1600536811017144 Text en © Maggini and White 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Maggini, Simona White, Peter S. [μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2) N,C (2):κ(2) C (2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2) O,O′)palladium(II)](Pd—Pd) |
| title | [μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2)
N,C
(2):κ(2)
C
(2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2)
O,O′)palladium(II)](Pd—Pd) |
| title_full | [μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2)
N,C
(2):κ(2)
C
(2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2)
O,O′)palladium(II)](Pd—Pd) |
| title_fullStr | [μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2)
N,C
(2):κ(2)
C
(2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2)
O,O′)palladium(II)](Pd—Pd) |
| title_full_unstemmed | [μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2)
N,C
(2):κ(2)
C
(2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2)
O,O′)palladium(II)](Pd—Pd) |
| title_short | [μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2)
N,C
(2):κ(2)
C
(2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2)
O,O′)palladium(II)](Pd—Pd) |
| title_sort | [μ-1,3-dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2)
n,c
(2):κ(2)
c
(2),n′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2)
o,o′)palladium(ii)](pd—pd) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120612/ https://www.ncbi.nlm.nih.gov/pubmed/21754640 http://dx.doi.org/10.1107/S1600536811017144 |
| work_keys_str_mv | AT magginisimona m13dioxo13bispyridin2ylpropane22diidok2nc2k2c2nbis13diphenylpropane13dionatok2oopalladiumiipdpd AT whitepeters m13dioxo13bispyridin2ylpropane22diidok2nc2k2c2nbis13diphenylpropane13dionatok2oopalladiumiipdpd |