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[μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ(2) N,C (2):κ(2) C (2),N′]bis[(1,3-diphenylpropane-1,3-dionato-κ(2) O,O′)palladium(II)](Pd—Pd)

The title compound, [Pd(2)(C(13)H(8)N(2)O(2))(C(15)H(11)O(2))(2)], crystallized from a mixture of ethanol and n-hexa­nes. The structure is the first example of β-diketonate in a dianionic κ(2) C-coordination complex containing a Pd(II)—Pd(II) bond. Both Pd(II) atoms adopt a pseudo square-planar coor...

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Detalles Bibliográficos
Autores principales: Maggini, Simona, White, Peter S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120612/
https://www.ncbi.nlm.nih.gov/pubmed/21754640
http://dx.doi.org/10.1107/S1600536811017144