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Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) monohydrate
In the title Cu(II) complex, [Cu(C(7)H(3)NO(4))(C(6)H(5)NO(2))(H(2)O)]·H(2)O, the environment of the Cu(2+) ion is a distorted square pyramid with the axial site occupied by the O atom from the coordinated water molecule and the square base formed by two O and two N atoms from the tridentate anion...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120614/ https://www.ncbi.nlm.nih.gov/pubmed/21754683 http://dx.doi.org/10.1107/S160053681101926X |
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author | Chen, Ting Ting Shang, Yan Fang Xi, Xia Zhang, Yue Hua Wang, Nan Ping |
author_facet | Chen, Ting Ting Shang, Yan Fang Xi, Xia Zhang, Yue Hua Wang, Nan Ping |
author_sort | Chen, Ting Ting |
collection | PubMed |
description | In the title Cu(II) complex, [Cu(C(7)H(3)NO(4))(C(6)H(5)NO(2))(H(2)O)]·H(2)O, the environment of the Cu(2+) ion is a distorted square pyramid with the axial site occupied by the O atom from the coordinated water molecule and the square base formed by two O and two N atoms from the tridentate anion and the neutral monodentate pyridine-3-carboxylic acid ligand. O—H⋯O hydrogen bonds, as well as π–π interactions [centroid–centroid distance = 3.945 (3) Å] contribute to the stabilization of this structure. |
format | Online Article Text |
id | pubmed-3120614 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31206142011-07-13 Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) monohydrate Chen, Ting Ting Shang, Yan Fang Xi, Xia Zhang, Yue Hua Wang, Nan Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Cu(II) complex, [Cu(C(7)H(3)NO(4))(C(6)H(5)NO(2))(H(2)O)]·H(2)O, the environment of the Cu(2+) ion is a distorted square pyramid with the axial site occupied by the O atom from the coordinated water molecule and the square base formed by two O and two N atoms from the tridentate anion and the neutral monodentate pyridine-3-carboxylic acid ligand. O—H⋯O hydrogen bonds, as well as π–π interactions [centroid–centroid distance = 3.945 (3) Å] contribute to the stabilization of this structure. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120614/ /pubmed/21754683 http://dx.doi.org/10.1107/S160053681101926X Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Ting Ting Shang, Yan Fang Xi, Xia Zhang, Yue Hua Wang, Nan Ping Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) monohydrate |
title | Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) monohydrate |
title_full | Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) monohydrate |
title_fullStr | Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) monohydrate |
title_full_unstemmed | Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) monohydrate |
title_short | Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) monohydrate |
title_sort | aqua(pyridine-3-carboxylic acid-κn)(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))copper(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120614/ https://www.ncbi.nlm.nih.gov/pubmed/21754683 http://dx.doi.org/10.1107/S160053681101926X |
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