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Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II)
In the title compound, [Cu(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and exhibits an octahedral coordination defined by two O atoms from water molecules in the axial positions and by four O atoms from two deprotonated coumarin-3-carboxylic acid lig...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120618/ https://www.ncbi.nlm.nih.gov/pubmed/21754664 http://dx.doi.org/10.1107/S1600536811018708 |
Sumario: | In the title compound, [Cu(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and exhibits an octahedral coordination defined by two O atoms from water molecules in the axial positions and by four O atoms from two deprotonated coumarin-3-carboxylic acid ligands in the equatorial positions. The angles around the Cu(II) atom vary between 85.32 (6) and 94.68 (6)°. The Cu—O bond distances between the Cu(II) atom and the O atoms vary between 1.9424 (14) and 2.3229 (15) Å. The layers interdigitate via face-to-face aromatic interactions [3.6490 (8) Å] between coumarin moieties such that the interlayer separation is 10.460 (2) Å, i.e. the length of the c axis. O—H⋯O hydrogen bonds between the H atoms of coordinated water molecules and the O atoms of carboxylate groups link the complex molecules into layers parallel to the ab plane. |
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