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Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II)
In the title compound, [Cu(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and exhibits an octahedral coordination defined by two O atoms from water molecules in the axial positions and by four O atoms from two deprotonated coumarin-3-carboxylic acid lig...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120618/ https://www.ncbi.nlm.nih.gov/pubmed/21754664 http://dx.doi.org/10.1107/S1600536811018708 |
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author | Cui, Yue Gao, Qian Wang, Huan-Huan Wang, Lin Xie, Ya-Bo |
author_facet | Cui, Yue Gao, Qian Wang, Huan-Huan Wang, Lin Xie, Ya-Bo |
author_sort | Cui, Yue |
collection | PubMed |
description | In the title compound, [Cu(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and exhibits an octahedral coordination defined by two O atoms from water molecules in the axial positions and by four O atoms from two deprotonated coumarin-3-carboxylic acid ligands in the equatorial positions. The angles around the Cu(II) atom vary between 85.32 (6) and 94.68 (6)°. The Cu—O bond distances between the Cu(II) atom and the O atoms vary between 1.9424 (14) and 2.3229 (15) Å. The layers interdigitate via face-to-face aromatic interactions [3.6490 (8) Å] between coumarin moieties such that the interlayer separation is 10.460 (2) Å, i.e. the length of the c axis. O—H⋯O hydrogen bonds between the H atoms of coordinated water molecules and the O atoms of carboxylate groups link the complex molecules into layers parallel to the ab plane. |
format | Online Article Text |
id | pubmed-3120618 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31206182011-07-13 Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II) Cui, Yue Gao, Qian Wang, Huan-Huan Wang, Lin Xie, Ya-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and exhibits an octahedral coordination defined by two O atoms from water molecules in the axial positions and by four O atoms from two deprotonated coumarin-3-carboxylic acid ligands in the equatorial positions. The angles around the Cu(II) atom vary between 85.32 (6) and 94.68 (6)°. The Cu—O bond distances between the Cu(II) atom and the O atoms vary between 1.9424 (14) and 2.3229 (15) Å. The layers interdigitate via face-to-face aromatic interactions [3.6490 (8) Å] between coumarin moieties such that the interlayer separation is 10.460 (2) Å, i.e. the length of the c axis. O—H⋯O hydrogen bonds between the H atoms of coordinated water molecules and the O atoms of carboxylate groups link the complex molecules into layers parallel to the ab plane. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120618/ /pubmed/21754664 http://dx.doi.org/10.1107/S1600536811018708 Text en © Cui et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cui, Yue Gao, Qian Wang, Huan-Huan Wang, Lin Xie, Ya-Bo Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II) |
title | Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II) |
title_full | Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II) |
title_fullStr | Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II) |
title_full_unstemmed | Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II) |
title_short | Diaquabis(2-oxo-2H-chromene-3-carboxylato)copper(II) |
title_sort | diaquabis(2-oxo-2h-chromene-3-carboxylato)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120618/ https://www.ncbi.nlm.nih.gov/pubmed/21754664 http://dx.doi.org/10.1107/S1600536811018708 |
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