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Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II)

In the title compound, [Cu(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and exhibits an octa­hedral coordination defined by two O atoms from water mol­ecules in the axial positions and by four O atoms from two deprotonated coumarin-3-carb­oxy­lic acid lig...

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Autores principales: Cui, Yue, Gao, Qian, Wang, Huan-Huan, Wang, Lin, Xie, Ya-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120618/
https://www.ncbi.nlm.nih.gov/pubmed/21754664
http://dx.doi.org/10.1107/S1600536811018708
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author Cui, Yue
Gao, Qian
Wang, Huan-Huan
Wang, Lin
Xie, Ya-Bo
author_facet Cui, Yue
Gao, Qian
Wang, Huan-Huan
Wang, Lin
Xie, Ya-Bo
author_sort Cui, Yue
collection PubMed
description In the title compound, [Cu(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and exhibits an octa­hedral coordination defined by two O atoms from water mol­ecules in the axial positions and by four O atoms from two deprotonated coumarin-3-carb­oxy­lic acid ligands in the equatorial positions. The angles around the Cu(II) atom vary between 85.32 (6) and 94.68 (6)°. The Cu—O bond distances between the Cu(II) atom and the O atoms vary between 1.9424 (14) and 2.3229 (15) Å. The layers inter­digitate via face-to-face aromatic inter­actions [3.6490 (8) Å] between coumarin moieties such that the inter­layer separation is 10.460 (2) Å, i.e. the length of the c axis. O—H⋯O hydrogen bonds between the H atoms of coordinated water mol­ecules and the O atoms of carboxyl­ate groups link the complex mol­ecules into layers parallel to the ab plane.
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spelling pubmed-31206182011-07-13 Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II) Cui, Yue Gao, Qian Wang, Huan-Huan Wang, Lin Xie, Ya-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(10)H(5)O(4))(2)(H(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and exhibits an octa­hedral coordination defined by two O atoms from water mol­ecules in the axial positions and by four O atoms from two deprotonated coumarin-3-carb­oxy­lic acid ligands in the equatorial positions. The angles around the Cu(II) atom vary between 85.32 (6) and 94.68 (6)°. The Cu—O bond distances between the Cu(II) atom and the O atoms vary between 1.9424 (14) and 2.3229 (15) Å. The layers inter­digitate via face-to-face aromatic inter­actions [3.6490 (8) Å] between coumarin moieties such that the inter­layer separation is 10.460 (2) Å, i.e. the length of the c axis. O—H⋯O hydrogen bonds between the H atoms of coordinated water mol­ecules and the O atoms of carboxyl­ate groups link the complex mol­ecules into layers parallel to the ab plane. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120618/ /pubmed/21754664 http://dx.doi.org/10.1107/S1600536811018708 Text en © Cui et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Yue
Gao, Qian
Wang, Huan-Huan
Wang, Lin
Xie, Ya-Bo
Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II)
title Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II)
title_full Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II)
title_fullStr Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II)
title_full_unstemmed Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II)
title_short Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II)
title_sort diaqua­bis­(2-oxo-2h-chromene-3-carboxyl­ato)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120618/
https://www.ncbi.nlm.nih.gov/pubmed/21754664
http://dx.doi.org/10.1107/S1600536811018708
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