Chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) C (1),N)tris­(trimethyl­phos­phane-κP)iron

The title compound, [Fe(C(7)H(5)FN)Cl(C(3)H(9)P)(3)], was obtained as a product of the reaction of [Fe(Me(3)P)(4)] with a molar equivalent of (2-chloro-6-fluoro­phen­yl)methanimine in diethyl ether. This compound is sensitive to air, and rapidly decomposes when exposed to air for a few minutes. The...

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Detalles Bibliográficos
Autores principales: Xu, Xiaofeng, Li, Xiaoyan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120623/
https://www.ncbi.nlm.nih.gov/pubmed/21754587
http://dx.doi.org/10.1107/S1600536811015030
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author Xu, Xiaofeng
Li, Xiaoyan
author_facet Xu, Xiaofeng
Li, Xiaoyan
author_sort Xu, Xiaofeng
collection PubMed
description The title compound, [Fe(C(7)H(5)FN)Cl(C(3)H(9)P)(3)], was obtained as a product of the reaction of [Fe(Me(3)P)(4)] with a molar equivalent of (2-chloro-6-fluoro­phen­yl)methanimine in diethyl ether. This compound is sensitive to air, and rapidly decomposes when exposed to air for a few minutes. The Fe atom has an octa­hedral coordination geometry in which the bidentate fluoro­phenyl methanimine ligand forms the equatorial plane with the Cl atom and one of the trimethyl­phosphane ligands. The other two trimethyl­phosphane ligands are located in the axial positions. In the crystal, an N—H⋯Cl hydrogen bond occurs.
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spelling pubmed-31206232011-07-13 Chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) C (1),N)tris­(trimethyl­phos­phane-κP)iron Xu, Xiaofeng Li, Xiaoyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(7)H(5)FN)Cl(C(3)H(9)P)(3)], was obtained as a product of the reaction of [Fe(Me(3)P)(4)] with a molar equivalent of (2-chloro-6-fluoro­phen­yl)methanimine in diethyl ether. This compound is sensitive to air, and rapidly decomposes when exposed to air for a few minutes. The Fe atom has an octa­hedral coordination geometry in which the bidentate fluoro­phenyl methanimine ligand forms the equatorial plane with the Cl atom and one of the trimethyl­phosphane ligands. The other two trimethyl­phosphane ligands are located in the axial positions. In the crystal, an N—H⋯Cl hydrogen bond occurs. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120623/ /pubmed/21754587 http://dx.doi.org/10.1107/S1600536811015030 Text en © Xu and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Xiaofeng
Li, Xiaoyan
Chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) C (1),N)tris­(trimethyl­phos­phane-κP)iron
title Chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) C (1),N)tris­(trimethyl­phos­phane-κP)iron
title_full Chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) C (1),N)tris­(trimethyl­phos­phane-κP)iron
title_fullStr Chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) C (1),N)tris­(trimethyl­phos­phane-κP)iron
title_full_unstemmed Chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) C (1),N)tris­(trimethyl­phos­phane-κP)iron
title_short Chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) C (1),N)tris­(trimethyl­phos­phane-κP)iron
title_sort chlorido(2-imino­methyl-3-fluoro­phenyl-κ(2) c (1),n)tris­(trimethyl­phos­phane-κp)iron
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120623/
https://www.ncbi.nlm.nih.gov/pubmed/21754587
http://dx.doi.org/10.1107/S1600536811015030
work_keys_str_mv AT xuxiaofeng chlorido2iminomethyl3fluorophenylk2c1ntristrimethylphosphanekpiron
AT lixiaoyan chlorido2iminomethyl3fluorophenylk2c1ntristrimethylphosphanekpiron

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