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trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II)

In the title complex, [CuCl(2)(C(17)H(11)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center. It exhibits a distorted octa­hedral coordination geometry defined by two chloride anions at trans sites and four 3-pyridyl N atoms at equatorial sites from two (6-nicotinoyl-2-pyrid­yl)(3-pyrid­...

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Autores principales: Qiang, Hong, Zhang, Fan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120631/
https://www.ncbi.nlm.nih.gov/pubmed/21754646
http://dx.doi.org/10.1107/S1600536811017685
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author Qiang, Hong
Zhang, Fan
author_facet Qiang, Hong
Zhang, Fan
author_sort Qiang, Hong
collection PubMed
description In the title complex, [CuCl(2)(C(17)H(11)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center. It exhibits a distorted octa­hedral coordination geometry defined by two chloride anions at trans sites and four 3-pyridyl N atoms at equatorial sites from two (6-nicotinoyl-2-pyrid­yl)(3-pyrid­yl)methanone ligands. The (6-nicotinoyl-2-pyrid­yl)(3-pyrid­yl)methanone ligand can be viewed as having two pendant 3-pyridyl rings attached to a central pyridyl skeleton via separate carbonyl bridges, acting in a κ(2) N,N′-chelating mode with its 3-pyridyl N atoms bound to the Cu(II) ion. The pendant 3-pyridyl rings make a dihedral angle of 80.76 (5)°. In the crystal, mol­ecules are linked through inter­molecular C—H⋯π and C—H⋯O inter­actions, forming a three-dimentional framework.
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spelling pubmed-31206312011-07-13 trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II) Qiang, Hong Zhang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(17)H(11)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center. It exhibits a distorted octa­hedral coordination geometry defined by two chloride anions at trans sites and four 3-pyridyl N atoms at equatorial sites from two (6-nicotinoyl-2-pyrid­yl)(3-pyrid­yl)methanone ligands. The (6-nicotinoyl-2-pyrid­yl)(3-pyrid­yl)methanone ligand can be viewed as having two pendant 3-pyridyl rings attached to a central pyridyl skeleton via separate carbonyl bridges, acting in a κ(2) N,N′-chelating mode with its 3-pyridyl N atoms bound to the Cu(II) ion. The pendant 3-pyridyl rings make a dihedral angle of 80.76 (5)°. In the crystal, mol­ecules are linked through inter­molecular C—H⋯π and C—H⋯O inter­actions, forming a three-dimentional framework. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120631/ /pubmed/21754646 http://dx.doi.org/10.1107/S1600536811017685 Text en © Qiang and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qiang, Hong
Zhang, Fan
trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II)
title trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II)
title_full trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II)
title_fullStr trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II)
title_full_unstemmed trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II)
title_short trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II)
title_sort trans-dichloridobis[(6-nicotinoyl-2-pyridyl-κn (6))(3-pyridyl-κn)methanone]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120631/
https://www.ncbi.nlm.nih.gov/pubmed/21754646
http://dx.doi.org/10.1107/S1600536811017685
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