Cargando…
trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II)
In the title complex, [CuCl(2)(C(17)H(11)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center. It exhibits a distorted octahedral coordination geometry defined by two chloride anions at trans sites and four 3-pyridyl N atoms at equatorial sites from two (6-nicotinoyl-2-pyridyl)(3-pyrid...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120631/ https://www.ncbi.nlm.nih.gov/pubmed/21754646 http://dx.doi.org/10.1107/S1600536811017685 |
_version_ | 1782206722598764544 |
---|---|
author | Qiang, Hong Zhang, Fan |
author_facet | Qiang, Hong Zhang, Fan |
author_sort | Qiang, Hong |
collection | PubMed |
description | In the title complex, [CuCl(2)(C(17)H(11)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center. It exhibits a distorted octahedral coordination geometry defined by two chloride anions at trans sites and four 3-pyridyl N atoms at equatorial sites from two (6-nicotinoyl-2-pyridyl)(3-pyridyl)methanone ligands. The (6-nicotinoyl-2-pyridyl)(3-pyridyl)methanone ligand can be viewed as having two pendant 3-pyridyl rings attached to a central pyridyl skeleton via separate carbonyl bridges, acting in a κ(2) N,N′-chelating mode with its 3-pyridyl N atoms bound to the Cu(II) ion. The pendant 3-pyridyl rings make a dihedral angle of 80.76 (5)°. In the crystal, molecules are linked through intermolecular C—H⋯π and C—H⋯O interactions, forming a three-dimentional framework. |
format | Online Article Text |
id | pubmed-3120631 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31206312011-07-13 trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II) Qiang, Hong Zhang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(17)H(11)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center. It exhibits a distorted octahedral coordination geometry defined by two chloride anions at trans sites and four 3-pyridyl N atoms at equatorial sites from two (6-nicotinoyl-2-pyridyl)(3-pyridyl)methanone ligands. The (6-nicotinoyl-2-pyridyl)(3-pyridyl)methanone ligand can be viewed as having two pendant 3-pyridyl rings attached to a central pyridyl skeleton via separate carbonyl bridges, acting in a κ(2) N,N′-chelating mode with its 3-pyridyl N atoms bound to the Cu(II) ion. The pendant 3-pyridyl rings make a dihedral angle of 80.76 (5)°. In the crystal, molecules are linked through intermolecular C—H⋯π and C—H⋯O interactions, forming a three-dimentional framework. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120631/ /pubmed/21754646 http://dx.doi.org/10.1107/S1600536811017685 Text en © Qiang and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Qiang, Hong Zhang, Fan trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN (6))(3-pyridyl-κN)methanone]copper(II) |
title |
trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN
(6))(3-pyridyl-κN)methanone]copper(II) |
title_full |
trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN
(6))(3-pyridyl-κN)methanone]copper(II) |
title_fullStr |
trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN
(6))(3-pyridyl-κN)methanone]copper(II) |
title_full_unstemmed |
trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN
(6))(3-pyridyl-κN)methanone]copper(II) |
title_short |
trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN
(6))(3-pyridyl-κN)methanone]copper(II) |
title_sort | trans-dichloridobis[(6-nicotinoyl-2-pyridyl-κn
(6))(3-pyridyl-κn)methanone]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120631/ https://www.ncbi.nlm.nih.gov/pubmed/21754646 http://dx.doi.org/10.1107/S1600536811017685 |
work_keys_str_mv | AT qianghong transdichloridobis6nicotinoyl2pyridylkn63pyridylknmethanonecopperii AT zhangfan transdichloridobis6nicotinoyl2pyridylkn63pyridylknmethanonecopperii |