Metathesis of Fatty Acid Ester Derivatives in 1,1-Dialkyl and 1,2,3-Trialkyl Imidazolium Type Ionic Liquids

The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1–4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF(6)(−), BF(4)(−) and NTf(2)(−)) using the gas chromatographic technique. Best catalytic performance was obtaine...

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Detalles Bibliográficos
Autores principales: Thomas, Priya A., Marvey, Bassie B., Ebenso, Eno E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3131603/
https://www.ncbi.nlm.nih.gov/pubmed/21747719
http://dx.doi.org/10.3390/ijms12063989
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author Thomas, Priya A.
Marvey, Bassie B.
Ebenso, Eno E.
author_facet Thomas, Priya A.
Marvey, Bassie B.
Ebenso, Eno E.
author_sort Thomas, Priya A.
collection PubMed
description The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1–4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF(6)(−), BF(4)(−) and NTf(2)(−)) using the gas chromatographic technique. Best catalytic performance was obtained in [bdmim][X] type ionic liquids when compared with [bmim][X] type ionic liquids. Catalyst recycling studies were also carried out in the room temperature ionic liquids (RTILs) with catalysts 1–4 in order to explore their possible industrial application.
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spelling pubmed-31316032011-07-11 Metathesis of Fatty Acid Ester Derivatives in 1,1-Dialkyl and 1,2,3-Trialkyl Imidazolium Type Ionic Liquids Thomas, Priya A. Marvey, Bassie B. Ebenso, Eno E. Int J Mol Sci Article The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1–4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF(6)(−), BF(4)(−) and NTf(2)(−)) using the gas chromatographic technique. Best catalytic performance was obtained in [bdmim][X] type ionic liquids when compared with [bmim][X] type ionic liquids. Catalyst recycling studies were also carried out in the room temperature ionic liquids (RTILs) with catalysts 1–4 in order to explore their possible industrial application. Molecular Diversity Preservation International (MDPI) 2011-06-14 /pmc/articles/PMC3131603/ /pubmed/21747719 http://dx.doi.org/10.3390/ijms12063989 Text en © 2011 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0 This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Thomas, Priya A.
Marvey, Bassie B.
Ebenso, Eno E.
Metathesis of Fatty Acid Ester Derivatives in 1,1-Dialkyl and 1,2,3-Trialkyl Imidazolium Type Ionic Liquids
title Metathesis of Fatty Acid Ester Derivatives in 1,1-Dialkyl and 1,2,3-Trialkyl Imidazolium Type Ionic Liquids
title_full Metathesis of Fatty Acid Ester Derivatives in 1,1-Dialkyl and 1,2,3-Trialkyl Imidazolium Type Ionic Liquids
title_fullStr Metathesis of Fatty Acid Ester Derivatives in 1,1-Dialkyl and 1,2,3-Trialkyl Imidazolium Type Ionic Liquids
title_full_unstemmed Metathesis of Fatty Acid Ester Derivatives in 1,1-Dialkyl and 1,2,3-Trialkyl Imidazolium Type Ionic Liquids
title_short Metathesis of Fatty Acid Ester Derivatives in 1,1-Dialkyl and 1,2,3-Trialkyl Imidazolium Type Ionic Liquids
title_sort metathesis of fatty acid ester derivatives in 1,1-dialkyl and 1,2,3-trialkyl imidazolium type ionic liquids
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3131603/
https://www.ncbi.nlm.nih.gov/pubmed/21747719
http://dx.doi.org/10.3390/ijms12063989
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AT ebensoenoe metathesisoffattyacidesterderivativesin11dialkyland123trialkylimidazoliumtypeionicliquids

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