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High chemoselectivity in the phenol synthesis
Efforts to trap early intermediates of the gold-catalyzed phenol synthesis failed. Neither inter- nor intramolecularly offered vinyl groups, ketones or alcohols were able to intercept the gold carbenoid species. This indicates that the competing steps of the gold-catalyzed phenol synthesis are much...
Autores principales: | Rudolph, Matthias, McCreery, Melissa Q, Frey, Wolfgang, Hashmi, A Stephen K |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135103/ https://www.ncbi.nlm.nih.gov/pubmed/21804874 http://dx.doi.org/10.3762/bjoc.7.90 |
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