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Synthetic applications of gold-catalyzed ring expansions

The development of new methodologies catalyzed by late transition metals involving cycloisomerizations of strained rings can open new venues for the synthesis of structurally complex molecules with interesting biological activities. Herein we summarize, from both a synthetic as well as a mechanistic...

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Detalles Bibliográficos
Autores principales: Garayalde, David, Nevado, Cristina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3139417/
https://www.ncbi.nlm.nih.gov/pubmed/21772928
http://dx.doi.org/10.3762/bjoc.7.87
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author Garayalde, David
Nevado, Cristina
author_facet Garayalde, David
Nevado, Cristina
author_sort Garayalde, David
collection PubMed
description The development of new methodologies catalyzed by late transition metals involving cycloisomerizations of strained rings can open new venues for the synthesis of structurally complex molecules with interesting biological activities. Herein we summarize, from both a synthetic as well as a mechanistic point of view, the most recent developments in gold-catalyzed ring expansions.
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spelling pubmed-31394172011-07-19 Synthetic applications of gold-catalyzed ring expansions Garayalde, David Nevado, Cristina Beilstein J Org Chem Review The development of new methodologies catalyzed by late transition metals involving cycloisomerizations of strained rings can open new venues for the synthesis of structurally complex molecules with interesting biological activities. Herein we summarize, from both a synthetic as well as a mechanistic point of view, the most recent developments in gold-catalyzed ring expansions. Beilstein-Institut 2011-06-07 /pmc/articles/PMC3139417/ /pubmed/21772928 http://dx.doi.org/10.3762/bjoc.7.87 Text en Copyright © 2011, Garayalde and Nevado https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Garayalde, David
Nevado, Cristina
Synthetic applications of gold-catalyzed ring expansions
title Synthetic applications of gold-catalyzed ring expansions
title_full Synthetic applications of gold-catalyzed ring expansions
title_fullStr Synthetic applications of gold-catalyzed ring expansions
title_full_unstemmed Synthetic applications of gold-catalyzed ring expansions
title_short Synthetic applications of gold-catalyzed ring expansions
title_sort synthetic applications of gold-catalyzed ring expansions
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3139417/
https://www.ncbi.nlm.nih.gov/pubmed/21772928
http://dx.doi.org/10.3762/bjoc.7.87
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