A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation

[Image: see text] Reaction of 1,4-dipotassio-1,1,4,4-tetrakis(trimethylsilyl)tetramethyltetrasilane with [(Me(3)Si)(2)N](2)Sn led to the formation of an endocyclic distannene via the dimerization of a transient stannylene. In the presence of strong donor molecules such as PEt(3), the stannylene coul...

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Autores principales: Arp, Henning, Baumgartner, Judith, Marschner, Christoph, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2011
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3144678/
https://www.ncbi.nlm.nih.gov/pubmed/21438553
http://dx.doi.org/10.1021/ja1100883
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author Arp, Henning
Baumgartner, Judith
Marschner, Christoph
Müller, Thomas
author_facet Arp, Henning
Baumgartner, Judith
Marschner, Christoph
Müller, Thomas
author_sort Arp, Henning
collection PubMed
description [Image: see text] Reaction of 1,4-dipotassio-1,1,4,4-tetrakis(trimethylsilyl)tetramethyltetrasilane with [(Me(3)Si)(2)N](2)Sn led to the formation of an endocyclic distannene via the dimerization of a transient stannylene. In the presence of strong donor molecules such as PEt(3), the stannylene could be trapped as adduct. Reaction of the PEt(3) derivative with B(C(6)F(5))(3) gave rise to the formation of the stannylene B(C(6)F(5))(3) adduct.
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spelling pubmed-31446782011-07-28 A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation Arp, Henning Baumgartner, Judith Marschner, Christoph Müller, Thomas J Am Chem Soc [Image: see text] Reaction of 1,4-dipotassio-1,1,4,4-tetrakis(trimethylsilyl)tetramethyltetrasilane with [(Me(3)Si)(2)N](2)Sn led to the formation of an endocyclic distannene via the dimerization of a transient stannylene. In the presence of strong donor molecules such as PEt(3), the stannylene could be trapped as adduct. Reaction of the PEt(3) derivative with B(C(6)F(5))(3) gave rise to the formation of the stannylene B(C(6)F(5))(3) adduct. American Chemical Society 2011-03-25 2011-04-20 /pmc/articles/PMC3144678/ /pubmed/21438553 http://dx.doi.org/10.1021/ja1100883 Text en Copyright © 2011 American Chemical Society http://pubs.acs.org This is an open-access article distributed under the ACS AuthorChoice Terms & Conditions. Any use of this article, must conform to the terms of that license which are available at http://pubs.acs.org.
spellingShingle Arp, Henning
Baumgartner, Judith
Marschner, Christoph
Müller, Thomas
A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation
title A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation
title_full A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation
title_fullStr A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation
title_full_unstemmed A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation
title_short A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation
title_sort cyclic disilylated stannylene: synthesis, dimerization, and adduct formation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3144678/
https://www.ncbi.nlm.nih.gov/pubmed/21438553
http://dx.doi.org/10.1021/ja1100883
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