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Rearrangement/Fragmentation Reactions of Oligosilanes with Aluminum Chloride
[Image: see text] Reinvestigation of the Lewis acid catalyzed rearrangement of some open-chain permethyloligosilanes with the Al(Fe)Cl(3) catalyst system exhibited several cases of additional reactivity: namely, a fragmentation/cyclization reaction. Introduction of (trimethylsilyl)methyl substituent...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3148123/ https://www.ncbi.nlm.nih.gov/pubmed/21818171 http://dx.doi.org/10.1021/om1011165 |