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trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)

The bidentate 1,3,4-thia­diazole ligand substituted by two 2-pyridyl rings (denoted L) has been found to produce the new monomeric title complex, [Co(C(12)H(8)N(4)S)(2)(H(2)O)(2)](BF(4))(2). The thia­diazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]....

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Autores principales: Bentiss, Fouad, Capet, Frédéric, Lagrenée, Michel, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151744/
https://www.ncbi.nlm.nih.gov/pubmed/21836842
http://dx.doi.org/10.1107/S1600536811020125
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author Bentiss, Fouad
Capet, Frédéric
Lagrenée, Michel
Saadi, Mohamed
El Ammari, Lahcen
author_facet Bentiss, Fouad
Capet, Frédéric
Lagrenée, Michel
Saadi, Mohamed
El Ammari, Lahcen
author_sort Bentiss, Fouad
collection PubMed
description The bidentate 1,3,4-thia­diazole ligand substituted by two 2-pyridyl rings (denoted L) has been found to produce the new monomeric title complex, [Co(C(12)H(8)N(4)S)(2)(H(2)O)(2)](BF(4))(2). The thia­diazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]. The mean plane defined by these heterocyclic moieties makes a dihedral angle of 18.72 (6)° with the non-coordinated pyridyl ring. The Co(2+) cation, located at a crystallographic center of symmetry, is bonded to two ligands and two water mol­ecules in a trans configuration in an octa­hedral environment. The tetra­fluorido­­borate ions can be regarded as free anions in the crystal lattice. Nevertheless, they are involved in an infinite two-dimensional network along the [010] and [101] directions of O—H⋯F hydrogen bonds.
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spelling pubmed-31517442011-08-11 trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate) Bentiss, Fouad Capet, Frédéric Lagrenée, Michel Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The bidentate 1,3,4-thia­diazole ligand substituted by two 2-pyridyl rings (denoted L) has been found to produce the new monomeric title complex, [Co(C(12)H(8)N(4)S)(2)(H(2)O)(2)](BF(4))(2). The thia­diazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]. The mean plane defined by these heterocyclic moieties makes a dihedral angle of 18.72 (6)° with the non-coordinated pyridyl ring. The Co(2+) cation, located at a crystallographic center of symmetry, is bonded to two ligands and two water mol­ecules in a trans configuration in an octa­hedral environment. The tetra­fluorido­­borate ions can be regarded as free anions in the crystal lattice. Nevertheless, they are involved in an infinite two-dimensional network along the [010] and [101] directions of O—H⋯F hydrogen bonds. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151744/ /pubmed/21836842 http://dx.doi.org/10.1107/S1600536811020125 Text en © Bentiss et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bentiss, Fouad
Capet, Frédéric
Lagrenée, Michel
Saadi, Mohamed
El Ammari, Lahcen
trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)
title trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)
title_full trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)
title_fullStr trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)
title_full_unstemmed trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)
title_short trans-Diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(II) bis­(tetra­fluoridoborate)
title_sort trans-diaqua­bis­[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole]cobalt(ii) bis­(tetra­fluoridoborate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151744/
https://www.ncbi.nlm.nih.gov/pubmed/21836842
http://dx.doi.org/10.1107/S1600536811020125
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