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Acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate
In the structure of the title compound, [Fe{η(5)-C(5)(CH(3))(5)}(NCCH(3))(CO)(2)]BF(4), the arrangement of ligands around the Fe atom is in a pseudo-octahedral three-legged piano-stool fashion in which the pentamethylcyclopentadienyl (Cp*) ligand occupies three apical coordination sites, while...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151746/ https://www.ncbi.nlm.nih.gov/pubmed/21836908 http://dx.doi.org/10.1107/S1600536811021350 |
| _version_ | 1782209644461031424 |
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| author | M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Bala, Muhammad D. |
| author_facet | M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Bala, Muhammad D. |
| author_sort | M’thiruaine, Cyprian M. |
| collection | PubMed |
| description | In the structure of the title compound, [Fe{η(5)-C(5)(CH(3))(5)}(NCCH(3))(CO)(2)]BF(4), the arrangement of ligands around the Fe atom is in a pseudo-octahedral three-legged piano-stool fashion in which the pentamethylcyclopentadienyl (Cp*) ligand occupies three apical coordination sites, while the two carbonyl and one acetonitrile ligands form the basal axes of the coordination. The Fe—N bond length is 1.924 (3) Å and the Fe—Cp* centroid distance is 1.722 Å. |
| format | Online Article Text |
| id | pubmed-3151746 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31517462011-08-11 Acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Bala, Muhammad D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Fe{η(5)-C(5)(CH(3))(5)}(NCCH(3))(CO)(2)]BF(4), the arrangement of ligands around the Fe atom is in a pseudo-octahedral three-legged piano-stool fashion in which the pentamethylcyclopentadienyl (Cp*) ligand occupies three apical coordination sites, while the two carbonyl and one acetonitrile ligands form the basal axes of the coordination. The Fe—N bond length is 1.924 (3) Å and the Fe—Cp* centroid distance is 1.722 Å. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151746/ /pubmed/21836908 http://dx.doi.org/10.1107/S1600536811021350 Text en © M'thiruaine et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Bala, Muhammad D. Acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate |
| title | Acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate |
| title_full | Acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate |
| title_fullStr | Acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate |
| title_full_unstemmed | Acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate |
| title_short | Acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(II) tetrafluoridoborate |
| title_sort | acetonitriledicarbonyl(η(5)-pentamethylcyclopentadienyl)iron(ii) tetrafluoridoborate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151746/ https://www.ncbi.nlm.nih.gov/pubmed/21836908 http://dx.doi.org/10.1107/S1600536811021350 |
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