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Benzyl N-(2-hydroxy-1-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate
The molecule of the title compound, C(18)H(19)N(3)O(5), adopts a curved arrangement with the terminal benzene rings lying to the same side. The hydroxylbenzene ring is close to coplanar with the adjacent hydrazine residue [dihedral angle = 11.14 (12)°], an observation which correlates with the pre...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151747/ https://www.ncbi.nlm.nih.gov/pubmed/21837230 http://dx.doi.org/10.1107/S1600536811025128 |
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author | Tiekink, Edward R. T. de Souza, Marcus V. N. Pinheiro, Alessandra C. Wardell, Solange M. S. V. Wardell, James L. |
author_facet | Tiekink, Edward R. T. de Souza, Marcus V. N. Pinheiro, Alessandra C. Wardell, Solange M. S. V. Wardell, James L. |
author_sort | Tiekink, Edward R. T. |
collection | PubMed |
description | The molecule of the title compound, C(18)H(19)N(3)O(5), adopts a curved arrangement with the terminal benzene rings lying to the same side. The hydroxylbenzene ring is close to coplanar with the adjacent hydrazine residue [dihedral angle = 11.14 (12)°], an observation which correlates with the presence of an intramolecular O—H⋯N hydrogen bond. The benzyl ring forms a dihedral angle of 50.84 (13)° with the adjacent carbamate group. A twist in the molecule, at the chiral C atom, is reflected in the dihedral angle of 80.21 (12)° formed between the amide residues. In the crystal, two-dimensional arrays in the ac plane are mediated by O—H⋯O and N—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3151747 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31517472011-08-11 Benzyl N-(2-hydroxy-1-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate Tiekink, Edward R. T. de Souza, Marcus V. N. Pinheiro, Alessandra C. Wardell, Solange M. S. V. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(18)H(19)N(3)O(5), adopts a curved arrangement with the terminal benzene rings lying to the same side. The hydroxylbenzene ring is close to coplanar with the adjacent hydrazine residue [dihedral angle = 11.14 (12)°], an observation which correlates with the presence of an intramolecular O—H⋯N hydrogen bond. The benzyl ring forms a dihedral angle of 50.84 (13)° with the adjacent carbamate group. A twist in the molecule, at the chiral C atom, is reflected in the dihedral angle of 80.21 (12)° formed between the amide residues. In the crystal, two-dimensional arrays in the ac plane are mediated by O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3151747/ /pubmed/21837230 http://dx.doi.org/10.1107/S1600536811025128 Text en © Tiekink et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tiekink, Edward R. T. de Souza, Marcus V. N. Pinheiro, Alessandra C. Wardell, Solange M. S. V. Wardell, James L. Benzyl N-(2-hydroxy-1-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
title | Benzyl N-(2-hydroxy-1-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
title_full | Benzyl N-(2-hydroxy-1-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
title_fullStr | Benzyl N-(2-hydroxy-1-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
title_full_unstemmed | Benzyl N-(2-hydroxy-1-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
title_short | Benzyl N-(2-hydroxy-1-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
title_sort | benzyl n-(2-hydroxy-1-{n′-[(1e)-2-hydroxybenzylidene]hydrazinecarbonyl}ethyl)carbamate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151747/ https://www.ncbi.nlm.nih.gov/pubmed/21837230 http://dx.doi.org/10.1107/S1600536811025128 |
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