Bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(II)

The complete complex anion in the title salt, (C(11)H(19)N(2))(2)[Cu(C(4)N(2)S(2))(2)], has 2/m symmetry while the complete cation is generated by mirror symmetry with the non-H atoms of the alkyl chain lying on the plane. A square-planar geometry based on an S(4) donor set is found in the anion; th...

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Detalles Bibliográficos
Autores principales: Liu, Qi, Liu, Jianlan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151750/
https://www.ncbi.nlm.nih.gov/pubmed/21836901
http://dx.doi.org/10.1107/S1600536811021611
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author Liu, Qi
Liu, Jianlan
author_facet Liu, Qi
Liu, Jianlan
author_sort Liu, Qi
collection PubMed
description The complete complex anion in the title salt, (C(11)H(19)N(2))(2)[Cu(C(4)N(2)S(2))(2)], has 2/m symmetry while the complete cation is generated by mirror symmetry with the non-H atoms of the alkyl chain lying on the plane. A square-planar geometry based on an S(4) donor set is found in the anion; the Cu—S distance is 2.2663 (5) Å. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the ions into layers in the bc plane comprising alternating rows of cations and anions.
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spelling pubmed-31517502011-08-11 Bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(II) Liu, Qi Liu, Jianlan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete complex anion in the title salt, (C(11)H(19)N(2))(2)[Cu(C(4)N(2)S(2))(2)], has 2/m symmetry while the complete cation is generated by mirror symmetry with the non-H atoms of the alkyl chain lying on the plane. A square-planar geometry based on an S(4) donor set is found in the anion; the Cu—S distance is 2.2663 (5) Å. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the ions into layers in the bc plane comprising alternating rows of cations and anions. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151750/ /pubmed/21836901 http://dx.doi.org/10.1107/S1600536811021611 Text en © Liu and Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Qi
Liu, Jianlan
Bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(II)
title Bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(II)
title_full Bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(II)
title_fullStr Bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(II)
title_full_unstemmed Bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(II)
title_short Bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(II)
title_sort bis(4-amino-1-hexylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato)cuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151750/
https://www.ncbi.nlm.nih.gov/pubmed/21836901
http://dx.doi.org/10.1107/S1600536811021611
work_keys_str_mv AT liuqi bis4amino1hexylpyridiniumbis12dicyanoethene12dithiolatocuprateii
AT liujianlan bis4amino1hexylpyridiniumbis12dicyanoethene12dithiolatocuprateii

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