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{N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)zinc(II)
In the title compound, [Zn(NCS)(2)(C(10)H(15)N(3))], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN(5) trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the li...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151752/ https://www.ncbi.nlm.nih.gov/pubmed/21836839 http://dx.doi.org/10.1107/S1600536811019945 |
| _version_ | 1782209646470103040 |
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| author | Li, Xian-Wen |
| author_facet | Li, Xian-Wen |
| author_sort | Li, Xian-Wen |
| collection | PubMed |
| description | In the title compound, [Zn(NCS)(2)(C(10)H(15)N(3))], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN(5) trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the ligand is disordered over two sets of sites in a 0.655 (12):0.345 (12) ratio. In the crystal, molecules are linked by N—H⋯S hydrogen bonds, generating [100] chains. |
| format | Online Article Text |
| id | pubmed-3151752 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31517522011-08-11 {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)zinc(II) Li, Xian-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(NCS)(2)(C(10)H(15)N(3))], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN(5) trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the ligand is disordered over two sets of sites in a 0.655 (12):0.345 (12) ratio. In the crystal, molecules are linked by N—H⋯S hydrogen bonds, generating [100] chains. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151752/ /pubmed/21836839 http://dx.doi.org/10.1107/S1600536811019945 Text en © Xian-Wen Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Xian-Wen {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_full | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_fullStr | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_full_unstemmed | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_short | {N-Methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_sort | {n-methyl-n′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
n,n′,n′′}bis(thiocyanato-κn)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151752/ https://www.ncbi.nlm.nih.gov/pubmed/21836839 http://dx.doi.org/10.1107/S1600536811019945 |
| work_keys_str_mv | AT lixianwen nmethyln1pyridin2ylethylideneethane12diaminek3nnnbisthiocyanatoknzincii |