(Dimethyl sulfoxide-κO)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κO (1))tin(IV)

In the title mononuclear complex, [Sn(CH(3))(3)(C(7)H(5)N(2)O(6))(C(2)H(6)OS)], the Sn(IV) ion is coordinated by three methyl groups in the equatorial plane, and by an O atom from a 2-methyl-3,5-dinitrobenzoate ligand and a dimethyl sulfoxide ligand in the axial sites, to form a slightly distorted t...

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Autores principales: Danish, Muhammed, Ghafoor, Sabiha, Ahmad, Nazir, Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151753/
https://www.ncbi.nlm.nih.gov/pubmed/21836907
http://dx.doi.org/10.1107/S1600536811022240
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author Danish, Muhammed
Ghafoor, Sabiha
Ahmad, Nazir
Starosta, Wojciech
Leciejewicz, Janusz
author_facet Danish, Muhammed
Ghafoor, Sabiha
Ahmad, Nazir
Starosta, Wojciech
Leciejewicz, Janusz
author_sort Danish, Muhammed
collection PubMed
description In the title mononuclear complex, [Sn(CH(3))(3)(C(7)H(5)N(2)O(6))(C(2)H(6)OS)], the Sn(IV) ion is coordinated by three methyl groups in the equatorial plane, and by an O atom from a 2-methyl-3,5-dinitrobenzoate ligand and a dimethyl sulfoxide ligand in the axial sites, to form a slightly distorted trigonal–bipyramidal environment. The O atoms of one of the nitro groups are disordered over two sets of sites, with refined occupancies of 0.55 (4) and 0.45 (4). The closest inter­molecular inter­action is a weak C—H⋯O hydrogen bond.
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spelling pubmed-31517532011-08-11 (Dimethyl sulfoxide-κO)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κO (1))tin(IV) Danish, Muhammed Ghafoor, Sabiha Ahmad, Nazir Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Sn(CH(3))(3)(C(7)H(5)N(2)O(6))(C(2)H(6)OS)], the Sn(IV) ion is coordinated by three methyl groups in the equatorial plane, and by an O atom from a 2-methyl-3,5-dinitrobenzoate ligand and a dimethyl sulfoxide ligand in the axial sites, to form a slightly distorted trigonal–bipyramidal environment. The O atoms of one of the nitro groups are disordered over two sets of sites, with refined occupancies of 0.55 (4) and 0.45 (4). The closest inter­molecular inter­action is a weak C—H⋯O hydrogen bond. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151753/ /pubmed/21836907 http://dx.doi.org/10.1107/S1600536811022240 Text en © Danish et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Danish, Muhammed
Ghafoor, Sabiha
Ahmad, Nazir
Starosta, Wojciech
Leciejewicz, Janusz
(Dimethyl sulfoxide-κO)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κO (1))tin(IV)
title (Dimethyl sulfoxide-κO)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κO (1))tin(IV)
title_full (Dimethyl sulfoxide-κO)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κO (1))tin(IV)
title_fullStr (Dimethyl sulfoxide-κO)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κO (1))tin(IV)
title_full_unstemmed (Dimethyl sulfoxide-κO)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κO (1))tin(IV)
title_short (Dimethyl sulfoxide-κO)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κO (1))tin(IV)
title_sort (dimethyl sulfoxide-κo)trimeth­yl(2-methyl-3,5-dinitro­benzoato-κo (1))tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151753/
https://www.ncbi.nlm.nih.gov/pubmed/21836907
http://dx.doi.org/10.1107/S1600536811022240
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