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Ethyl 1-[2-(1H-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate
In the title compound, C(28)H(26)N(4)O(4), the tetrahydropyridine ring adopts a boat conformation. The two phenyl rings form dihedral angles of 88.64 (8) and 59.28 (10)° with the best plane through the tetrahydropyridine ring. The dihedral angle between the two phenyl rings is 82.55 (10)°. The b...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151759/ https://www.ncbi.nlm.nih.gov/pubmed/21836985 http://dx.doi.org/10.1107/S1600536811020241 |
| _version_ | 1782209648048209920 |
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| author | Aridoss, G. Sundaramoorthy, S. Velmurugan, D. Jeong, Y. T. |
| author_facet | Aridoss, G. Sundaramoorthy, S. Velmurugan, D. Jeong, Y. T. |
| author_sort | Aridoss, G. |
| collection | PubMed |
| description | In the title compound, C(28)H(26)N(4)O(4), the tetrahydropyridine ring adopts a boat conformation. The two phenyl rings form dihedral angles of 88.64 (8) and 59.28 (10)° with the best plane through the tetrahydropyridine ring. The dihedral angle between the two phenyl rings is 82.55 (10)°. The benzotriazole ring system is essentially planar, with a maximum deviation of 0.009 (1) Å from the least-squares plane. The molecular conformation is stabilized by an intramolecular O—H⋯O hydrogen bond, generating an S(6) motif. |
| format | Online Article Text |
| id | pubmed-3151759 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31517592011-08-11 Ethyl 1-[2-(1H-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate Aridoss, G. Sundaramoorthy, S. Velmurugan, D. Jeong, Y. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(26)N(4)O(4), the tetrahydropyridine ring adopts a boat conformation. The two phenyl rings form dihedral angles of 88.64 (8) and 59.28 (10)° with the best plane through the tetrahydropyridine ring. The dihedral angle between the two phenyl rings is 82.55 (10)°. The benzotriazole ring system is essentially planar, with a maximum deviation of 0.009 (1) Å from the least-squares plane. The molecular conformation is stabilized by an intramolecular O—H⋯O hydrogen bond, generating an S(6) motif. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151759/ /pubmed/21836985 http://dx.doi.org/10.1107/S1600536811020241 Text en © Aridoss et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Aridoss, G. Sundaramoorthy, S. Velmurugan, D. Jeong, Y. T. Ethyl 1-[2-(1H-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate |
| title | Ethyl 1-[2-(1H-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate |
| title_full | Ethyl 1-[2-(1H-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate |
| title_fullStr | Ethyl 1-[2-(1H-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate |
| title_full_unstemmed | Ethyl 1-[2-(1H-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate |
| title_short | Ethyl 1-[2-(1H-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate |
| title_sort | ethyl 1-[2-(1h-benzotriazol-1-yl)acetyl]-4-hydroxy-2,6-diphenyl-1,2,5,6-tetrahydropyridine-3-carboxylate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151759/ https://www.ncbi.nlm.nih.gov/pubmed/21836985 http://dx.doi.org/10.1107/S1600536811020241 |
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