3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one

The asymmetric unit of the title compound, C(21)H(26)O(4)S, consists of two independent mol­ecules. In both mol­ecules, intra­molecular O—H⋯O hydrogen bonds stabilize the mol­ecular structure. In the crystal, each mol­ecule and its symmetry-related mol­ecule by twofold rotation form a dimer through...

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Autores principales: Asad, Mohammad, Oo, Chuan-Wei, Osman, Hasnah, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151761/
https://www.ncbi.nlm.nih.gov/pubmed/21837183
http://dx.doi.org/10.1107/S160053681102407X
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author Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Asad, Mohammad
collection PubMed
description The asymmetric unit of the title compound, C(21)H(26)O(4)S, consists of two independent mol­ecules. In both mol­ecules, intra­molecular O—H⋯O hydrogen bonds stabilize the mol­ecular structure. In the crystal, each mol­ecule and its symmetry-related mol­ecule by twofold rotation form a dimer through a pair of inter­molecular C—H⋯O hydrogen bonds. In one of the mol­ecules, the thio­phene group is disordered over two sets of sites with occupancies of 0.735 (3) and 0.265 (3).
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spelling pubmed-31517612011-08-11 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(26)O(4)S, consists of two independent mol­ecules. In both mol­ecules, intra­molecular O—H⋯O hydrogen bonds stabilize the mol­ecular structure. In the crystal, each mol­ecule and its symmetry-related mol­ecule by twofold rotation form a dimer through a pair of inter­molecular C—H⋯O hydrogen bonds. In one of the mol­ecules, the thio­phene group is disordered over two sets of sites with occupancies of 0.735 (3) and 0.265 (3). International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151761/ /pubmed/21837183 http://dx.doi.org/10.1107/S160053681102407X Text en © Asad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_full 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_fullStr 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_full_unstemmed 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_short 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_sort 3-hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(thiophen-3-yl)methyl]-5,5-dimethylcyclohex-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151761/
https://www.ncbi.nlm.nih.gov/pubmed/21837183
http://dx.doi.org/10.1107/S160053681102407X
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