Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc

In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen­yl]aniline ligands and two Cl atoms, resulting in a distorted tetra­hedral geometry. The ligands are mutually transoid wit...

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Detalles Bibliográficos
Autores principales: Leesakul, Nararak, Pakawatchai, Chaveng, Saithong, Saowanit, Tantirungrotechai, Yuthana, Kwanplod, Kwanchanok
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151768/
https://www.ncbi.nlm.nih.gov/pubmed/21836935
http://dx.doi.org/10.1107/S1600536811022884
Descripción
Sumario:In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen­yl]aniline ligands and two Cl atoms, resulting in a distorted tetra­hedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak inter­molecular C—H⋯Cl hydrogen bonds and π–π inter­actions, with centroid–centroid distances of 3.8452 (14) and 3.9932 (14) Å, are found in the crystal packing.

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