Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc

In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen­yl]aniline ligands and two Cl atoms, resulting in a distorted tetra­hedral geometry. The ligands are mutually transoid wit...

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Autores principales: Leesakul, Nararak, Pakawatchai, Chaveng, Saithong, Saowanit, Tantirungrotechai, Yuthana, Kwanplod, Kwanchanok
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151768/
https://www.ncbi.nlm.nih.gov/pubmed/21836935
http://dx.doi.org/10.1107/S1600536811022884
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author Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
Tantirungrotechai, Yuthana
Kwanplod, Kwanchanok
author_facet Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
Tantirungrotechai, Yuthana
Kwanplod, Kwanchanok
author_sort Leesakul, Nararak
collection PubMed
description In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen­yl]aniline ligands and two Cl atoms, resulting in a distorted tetra­hedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak inter­molecular C—H⋯Cl hydrogen bonds and π–π inter­actions, with centroid–centroid distances of 3.8452 (14) and 3.9932 (14) Å, are found in the crystal packing.
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spelling pubmed-31517682011-08-11 Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc Leesakul, Nararak Pakawatchai, Chaveng Saithong, Saowanit Tantirungrotechai, Yuthana Kwanplod, Kwanchanok Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen­yl]aniline ligands and two Cl atoms, resulting in a distorted tetra­hedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak inter­molecular C—H⋯Cl hydrogen bonds and π–π inter­actions, with centroid–centroid distances of 3.8452 (14) and 3.9932 (14) Å, are found in the crystal packing. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151768/ /pubmed/21836935 http://dx.doi.org/10.1107/S1600536811022884 Text en © Leesakul et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
Tantirungrotechai, Yuthana
Kwanplod, Kwanchanok
Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc
title Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc
title_full Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc
title_fullStr Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc
title_full_unstemmed Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc
title_short Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen­yl]aniline}zinc
title_sort dichloridobis{n,n-diethyl-4-[(pyridin-2-yl-κn)diazen­yl]aniline}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151768/
https://www.ncbi.nlm.nih.gov/pubmed/21836935
http://dx.doi.org/10.1107/S1600536811022884
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