Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium

In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol­ecules are linked through C—H⋯π inter­a...

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Detalles Bibliográficos
Autores principales: Saleh Salga, Muhammad, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151769/
https://www.ncbi.nlm.nih.gov/pubmed/21836911
http://dx.doi.org/10.1107/S1600536811022100
Descripción
Sumario:In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol­ecules are linked through C—H⋯π inter­actions into infinite chains along the a axis. The mol­ecules are further connected into a three-dimensional network via N—H⋯O, N—H⋯Cl and C—H⋯Cl inter­actions. The ethyl­ene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio.

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