Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium

In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol­ecules are linked through C—H⋯π inter­a...

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Detalles Bibliográficos
Autores principales: Saleh Salga, Muhammad, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151769/
https://www.ncbi.nlm.nih.gov/pubmed/21836911
http://dx.doi.org/10.1107/S1600536811022100
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author Saleh Salga, Muhammad
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Saleh Salga, Muhammad
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Saleh Salga, Muhammad
collection PubMed
description In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol­ecules are linked through C—H⋯π inter­actions into infinite chains along the a axis. The mol­ecules are further connected into a three-dimensional network via N—H⋯O, N—H⋯Cl and C—H⋯Cl inter­actions. The ethyl­ene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio.
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spelling pubmed-31517692011-08-11 Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium Saleh Salga, Muhammad Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol­ecules are linked through C—H⋯π inter­actions into infinite chains along the a axis. The mol­ecules are further connected into a three-dimensional network via N—H⋯O, N—H⋯Cl and C—H⋯Cl inter­actions. The ethyl­ene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151769/ /pubmed/21836911 http://dx.doi.org/10.1107/S1600536811022100 Text en © Saleh Salga et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Saleh Salga, Muhammad
Khaledi, Hamid
Mohd Ali, Hapipah
Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium
title Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium
title_full Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium
title_fullStr Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium
title_full_unstemmed Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium
title_short Dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium
title_sort dichlorido(4-meth­oxy-2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenol­ate)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151769/
https://www.ncbi.nlm.nih.gov/pubmed/21836911
http://dx.doi.org/10.1107/S1600536811022100
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AT mohdalihapipah dichlorido4methoxy22piperazin4ium1ylethyliminomethylphenolatecadmium

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