1-Methyl-2-({[(1-methyl-1H-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1H-benzimidazol-3-ium picrate

In the title molecular salt, C(24)H(24)N(5) (+)·C(6)H(2)N(3)O(7) (−), the dihedral angle between the benzimidazole rings of the cation is 5.041 (2)°. In the anion, the three nitro groups make dihedral angles of 2.468 (3), 12.795 (3) and 24.958 (4)° with respect to the central ring. In the crystal, w...

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Detalles Bibliográficos
Autores principales: Liu, Bin, Kou, Fan, Jia, Fei, Yuan, Jingkui, Wu, Huilu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151771/
https://www.ncbi.nlm.nih.gov/pubmed/21837185
http://dx.doi.org/10.1107/S1600536811024275
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author Liu, Bin
Kou, Fan
Jia, Fei
Yuan, Jingkui
Wu, Huilu
author_facet Liu, Bin
Kou, Fan
Jia, Fei
Yuan, Jingkui
Wu, Huilu
author_sort Liu, Bin
collection PubMed
description In the title molecular salt, C(24)H(24)N(5) (+)·C(6)H(2)N(3)O(7) (−), the dihedral angle between the benzimidazole rings of the cation is 5.041 (2)°. In the anion, the three nitro groups make dihedral angles of 2.468 (3), 12.795 (3) and 24.958 (4)° with respect to the central ring. In the crystal, weak aromatic π–π stacking [centroid–centroid distance = 3.599 (15) Å] consolidates the packing. In addition, an intra­molecular N—H⋯N hydrogen bond is observed.
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spelling pubmed-31517712011-08-11 1-Methyl-2-({[(1-methyl-1H-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1H-benzimidazol-3-ium picrate Liu, Bin Kou, Fan Jia, Fei Yuan, Jingkui Wu, Huilu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(24)H(24)N(5) (+)·C(6)H(2)N(3)O(7) (−), the dihedral angle between the benzimidazole rings of the cation is 5.041 (2)°. In the anion, the three nitro groups make dihedral angles of 2.468 (3), 12.795 (3) and 24.958 (4)° with respect to the central ring. In the crystal, weak aromatic π–π stacking [centroid–centroid distance = 3.599 (15) Å] consolidates the packing. In addition, an intra­molecular N—H⋯N hydrogen bond is observed. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151771/ /pubmed/21837185 http://dx.doi.org/10.1107/S1600536811024275 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Bin
Kou, Fan
Jia, Fei
Yuan, Jingkui
Wu, Huilu
1-Methyl-2-({[(1-methyl-1H-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1H-benzimidazol-3-ium picrate
title 1-Methyl-2-({[(1-methyl-1H-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1H-benzimidazol-3-ium picrate
title_full 1-Methyl-2-({[(1-methyl-1H-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1H-benzimidazol-3-ium picrate
title_fullStr 1-Methyl-2-({[(1-methyl-1H-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1H-benzimidazol-3-ium picrate
title_full_unstemmed 1-Methyl-2-({[(1-methyl-1H-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1H-benzimidazol-3-ium picrate
title_short 1-Methyl-2-({[(1-methyl-1H-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1H-benzimidazol-3-ium picrate
title_sort 1-methyl-2-({[(1-methyl-1h-benzimid­azol-2-yl)meth­yl](phen­yl)amino}­meth­yl)1h-benzimidazol-3-ium picrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151771/
https://www.ncbi.nlm.nih.gov/pubmed/21837185
http://dx.doi.org/10.1107/S1600536811024275
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