Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)

In the title compound, [Mn(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Schiff base acts as an N,N′,N"-tridentate ligand, forming two five-membered chelating rings with the Mn(II) atom. The distorted octa­hedral geometry around the metal atom is completed by two cis-positioned N-bound thio­cyanate lig...

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Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151779/
https://www.ncbi.nlm.nih.gov/pubmed/21836912
http://dx.doi.org/10.1107/S1600536811022124
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author Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description In the title compound, [Mn(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Schiff base acts as an N,N′,N"-tridentate ligand, forming two five-membered chelating rings with the Mn(II) atom. The distorted octa­hedral geometry around the metal atom is completed by two cis-positioned N-bound thio­cyanate ligands and one water mol­ecule. In the crystal, adjacent mol­ecules are linked through O—H⋯O, O—H⋯S and C—H⋯S hydrogen bonds into a three-dimensional supra-mol­ecular structure. An intra­molecular C—H⋯O hydrogen bond also occurs.
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spelling pubmed-31517792011-08-11 Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)manganese(II) Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Schiff base acts as an N,N′,N"-tridentate ligand, forming two five-membered chelating rings with the Mn(II) atom. The distorted octa­hedral geometry around the metal atom is completed by two cis-positioned N-bound thio­cyanate ligands and one water mol­ecule. In the crystal, adjacent mol­ecules are linked through O—H⋯O, O—H⋯S and C—H⋯S hydrogen bonds into a three-dimensional supra-mol­ecular structure. An intra­molecular C—H⋯O hydrogen bond also occurs. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151779/ /pubmed/21836912 http://dx.doi.org/10.1107/S1600536811022124 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)
title Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)
title_full Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)
title_fullStr Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)
title_full_unstemmed Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)
title_short Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)
title_sort aqua{2-(morpholin-4-yl)-n-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ(3) n,n′,n′′}bis­(thio­cyanato-κn)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151779/
https://www.ncbi.nlm.nih.gov/pubmed/21836912
http://dx.doi.org/10.1107/S1600536811022124
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