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(2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one

In the title compound C(22)H(24)O(2), the exocyclic C=C double bond is in an E configuration and the tert-butyl group is in an axial position on the cyclo­hexa­none ring. The cyclo­hexa­none ring in the dihydro­naphthalene fused-ring system adopts a half-chair conformation in both independent two mo...

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Detalles Bibliográficos
Autores principales: Akhazzane, Mohamed, Zouihri, Hafid, Daoudi, Maria, Kerbal, Abdelali, Al Houari, Ghali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151781/
https://www.ncbi.nlm.nih.gov/pubmed/21837196
http://dx.doi.org/10.1107/S1600536811021969
Descripción
Sumario:In the title compound C(22)H(24)O(2), the exocyclic C=C double bond is in an E configuration and the tert-butyl group is in an axial position on the cyclo­hexa­none ring. The cyclo­hexa­none ring in the dihydro­naphthalene fused-ring system adopts a half-chair conformation in both independent two mol­ecules in the asymetric unit. The benzene ring system is oriented angles of 43.97 (12) and 39.24 (12)° with respect to the naphthyl ring system in the two independent mol­ecules. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds and C—H⋯π inter­actions.