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(2E)-4-tert-Butyl-2-(4-methoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one
In the title compound C(22)H(24)O(2), the exocyclic C=C double bond is in an E configuration and the tert-butyl group is in an axial position on the cyclohexanone ring. The cyclohexanone ring in the dihydronaphthalene fused-ring system adopts a half-chair conformation in both independent two mo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151781/ https://www.ncbi.nlm.nih.gov/pubmed/21837196 http://dx.doi.org/10.1107/S1600536811021969 |
Sumario: | In the title compound C(22)H(24)O(2), the exocyclic C=C double bond is in an E configuration and the tert-butyl group is in an axial position on the cyclohexanone ring. The cyclohexanone ring in the dihydronaphthalene fused-ring system adopts a half-chair conformation in both independent two molecules in the asymetric unit. The benzene ring system is oriented angles of 43.97 (12) and 39.24 (12)° with respect to the naphthyl ring system in the two independent molecules. In the crystal, molecules are linked via C—H⋯O hydrogen bonds and C—H⋯π interactions. |
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