(2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one

In the title compound C(22)H(24)O(2), the exocyclic C=C double bond is in an E configuration and the tert-butyl group is in an axial position on the cyclo­hexa­none ring. The cyclo­hexa­none ring in the dihydro­naphthalene fused-ring system adopts a half-chair conformation in both independent two mo...

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Autores principales: Akhazzane, Mohamed, Zouihri, Hafid, Daoudi, Maria, Kerbal, Abdelali, Al Houari, Ghali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151781/
https://www.ncbi.nlm.nih.gov/pubmed/21837196
http://dx.doi.org/10.1107/S1600536811021969
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author Akhazzane, Mohamed
Zouihri, Hafid
Daoudi, Maria
Kerbal, Abdelali
Al Houari, Ghali
author_facet Akhazzane, Mohamed
Zouihri, Hafid
Daoudi, Maria
Kerbal, Abdelali
Al Houari, Ghali
author_sort Akhazzane, Mohamed
collection PubMed
description In the title compound C(22)H(24)O(2), the exocyclic C=C double bond is in an E configuration and the tert-butyl group is in an axial position on the cyclo­hexa­none ring. The cyclo­hexa­none ring in the dihydro­naphthalene fused-ring system adopts a half-chair conformation in both independent two mol­ecules in the asymetric unit. The benzene ring system is oriented angles of 43.97 (12) and 39.24 (12)° with respect to the naphthyl ring system in the two independent mol­ecules. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-31517812011-08-11 (2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one Akhazzane, Mohamed Zouihri, Hafid Daoudi, Maria Kerbal, Abdelali Al Houari, Ghali Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound C(22)H(24)O(2), the exocyclic C=C double bond is in an E configuration and the tert-butyl group is in an axial position on the cyclo­hexa­none ring. The cyclo­hexa­none ring in the dihydro­naphthalene fused-ring system adopts a half-chair conformation in both independent two mol­ecules in the asymetric unit. The benzene ring system is oriented angles of 43.97 (12) and 39.24 (12)° with respect to the naphthyl ring system in the two independent mol­ecules. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151781/ /pubmed/21837196 http://dx.doi.org/10.1107/S1600536811021969 Text en © Akhazzane et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akhazzane, Mohamed
Zouihri, Hafid
Daoudi, Maria
Kerbal, Abdelali
Al Houari, Ghali
(2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one
title (2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one
title_full (2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one
title_fullStr (2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one
title_full_unstemmed (2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one
title_short (2E)-4-tert-Butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2H)-one
title_sort (2e)-4-tert-butyl-2-(4-meth­oxy­benzyl­idene)-3,4-dihydro­naphthalen-1(2h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151781/
https://www.ncbi.nlm.nih.gov/pubmed/21837196
http://dx.doi.org/10.1107/S1600536811021969
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