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Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))iron(II)
In the title compound, [Fe(C(5)H(3)N(2)O(4))(2)(H(2)O)(2)], the Fe(II) ion lies on an inversion centre and is coordinated by two N and two O atoms from two 5-carboxy-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral geometry. An intramolecular O—H⋯O hydrogen b...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151786/ https://www.ncbi.nlm.nih.gov/pubmed/21836968 http://dx.doi.org/10.1107/S1600536811024779 |
| _version_ | 1782209655491002368 |
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| author | Du, Chao-Jun Song, Xing-Hua Wang, Li-Sheng Du, Chao-Ling |
| author_facet | Du, Chao-Jun Song, Xing-Hua Wang, Li-Sheng Du, Chao-Ling |
| author_sort | Du, Chao-Jun |
| collection | PubMed |
| description | In the title compound, [Fe(C(5)H(3)N(2)O(4))(2)(H(2)O)(2)], the Fe(II) ion lies on an inversion centre and is coordinated by two N and two O atoms from two 5-carboxy-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral geometry. An intramolecular O—H⋯O hydrogen bond occurs. In the crystal, intermolecular N—H⋯O and O—H⋯O hydrogen bonds form a three-dimensional network, which consolidates the packing. |
| format | Online Article Text |
| id | pubmed-3151786 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31517862011-08-11 Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))iron(II) Du, Chao-Jun Song, Xing-Hua Wang, Li-Sheng Du, Chao-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(3)N(2)O(4))(2)(H(2)O)(2)], the Fe(II) ion lies on an inversion centre and is coordinated by two N and two O atoms from two 5-carboxy-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral geometry. An intramolecular O—H⋯O hydrogen bond occurs. In the crystal, intermolecular N—H⋯O and O—H⋯O hydrogen bonds form a three-dimensional network, which consolidates the packing. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3151786/ /pubmed/21836968 http://dx.doi.org/10.1107/S1600536811024779 Text en © Du et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Du, Chao-Jun Song, Xing-Hua Wang, Li-Sheng Du, Chao-Ling Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))iron(II) |
| title | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))iron(II) |
| title_full | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))iron(II) |
| title_fullStr | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))iron(II) |
| title_full_unstemmed | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))iron(II) |
| title_short | Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))iron(II) |
| title_sort | diaquabis(5-carboxy-1h-imidazole-4-carboxylato-κ(2)
n
(3),o
(4))iron(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151786/ https://www.ncbi.nlm.nih.gov/pubmed/21836968 http://dx.doi.org/10.1107/S1600536811024779 |
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