Chloridobis(dimethyl­glyoximato-κ(2) N,N′)(4-methyl­pyridine-κN)cobalt(III) hemihydrate

In the title complex, [Co(C(4)H(7)N(2)O(2))(2)Cl(C(6)H(7)N)]·0.5H(2)O, the central Co(III) ion, chelated by four N atoms of the two bidenate glyoximate ligands, exhibits a slightly distorted octa­hedral geometry. The axial positions are occupied by a chloride ion and the 4-methyl­pyridine N atom. In...

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Detalles Bibliográficos
Autores principales: Amutha Selvi, Madhavan, Arun Kumar, Kannan, Dayalan, Arunachalam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151788/
https://www.ncbi.nlm.nih.gov/pubmed/21836853
http://dx.doi.org/10.1107/S1600536811020162
Descripción
Sumario:In the title complex, [Co(C(4)H(7)N(2)O(2))(2)Cl(C(6)H(7)N)]·0.5H(2)O, the central Co(III) ion, chelated by four N atoms of the two bidenate glyoximate ligands, exhibits a slightly distorted octa­hedral geometry. The axial positions are occupied by a chloride ion and the 4-methyl­pyridine N atom. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules in the crystal via the water mol­ecules, while the glyoximate ligands exhibit intra­molecular O—H⋯O hydrogen bonds.

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