2-Diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone

In the mol­ecule of the title compound, C(6)H(9)N(3)O(3)S, at 105 K, the six-membered ring is predominantly found in the chair conformation, with 1.89 (14)% in the boat conformation. In the crystal structure, there are five inter­molecular C—H⋯O=C and C—H⋯O=S contacts less than 2.6 Å, as well as a w...

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Detalles Bibliográficos
Autores principales: Kaupang, Åsmund, Görbitz, Carl Henrik, Hansen, Tore
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151793/
https://www.ncbi.nlm.nih.gov/pubmed/21837210
http://dx.doi.org/10.1107/S1600536811023774
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author Kaupang, Åsmund
Görbitz, Carl Henrik
Hansen, Tore
author_facet Kaupang, Åsmund
Görbitz, Carl Henrik
Hansen, Tore
author_sort Kaupang, Åsmund
collection PubMed
description In the mol­ecule of the title compound, C(6)H(9)N(3)O(3)S, at 105 K, the six-membered ring is predominantly found in the chair conformation, with 1.89 (14)% in the boat conformation. In the crystal structure, there are five inter­molecular C—H⋯O=C and C—H⋯O=S contacts less than 2.6 Å, as well as a weak C—H⋯N=N inter­action to the diazo group.
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spelling pubmed-31517932011-08-11 2-Diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone Kaupang, Åsmund Görbitz, Carl Henrik Hansen, Tore Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(6)H(9)N(3)O(3)S, at 105 K, the six-membered ring is predominantly found in the chair conformation, with 1.89 (14)% in the boat conformation. In the crystal structure, there are five inter­molecular C—H⋯O=C and C—H⋯O=S contacts less than 2.6 Å, as well as a weak C—H⋯N=N inter­action to the diazo group. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3151793/ /pubmed/21837210 http://dx.doi.org/10.1107/S1600536811023774 Text en © Kaupang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kaupang, Åsmund
Görbitz, Carl Henrik
Hansen, Tore
2-Diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone
title 2-Diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone
title_full 2-Diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone
title_fullStr 2-Diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone
title_full_unstemmed 2-Diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone
title_short 2-Diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone
title_sort 2-diazo-1-(1,1-dioxothio­morpholin-4-yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151793/
https://www.ncbi.nlm.nih.gov/pubmed/21837210
http://dx.doi.org/10.1107/S1600536811023774
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