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8-Chloro-6-iodo-2-phenylchromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethylformamide monosolvate
In the title compound, C(16)H(8)ClIN(2)O(2)·C(3)H(7)NO, the fused tricyclic pyrazolocoumarin ring and the N-phenyl ring are almost coplanar, the dihedral angle between them being 1.86 (9)°. In the crystal, these rings stack on top of each other via π–π interactions [centroid–centroid distances = 3...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151794/ https://www.ncbi.nlm.nih.gov/pubmed/21837089 http://dx.doi.org/10.1107/S1600536811022070 |
Sumario: | In the title compound, C(16)H(8)ClIN(2)O(2)·C(3)H(7)NO, the fused tricyclic pyrazolocoumarin ring and the N-phenyl ring are almost coplanar, the dihedral angle between them being 1.86 (9)°. In the crystal, these rings stack on top of each other via π–π interactions [centroid–centroid distances = 3.489 (2), 3.637 (2), 3.505 (2) and 3.662 (2) Å], forming infinite chains along the a axis. The chains are connected into layers parallel to ac plane through I⋯O interactions [3.0011 (18) Å] between pairs of symmetry-related molecules. The DMF solvent molecules are C—H⋯O bonded to this network. |
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