8-Chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethyl­formamide monosolvate

In the title compound, C(16)H(8)ClIN(2)O(2)·C(3)H(7)NO, the fused tricyclic pyrazolo­coumarin ring and the N-phenyl ring are almost coplanar, the dihedral angle between them being 1.86 (9)°. In the crystal, these rings stack on top of each other via π–π inter­actions [centroid–centroid distances = 3...

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Autores principales: Lokhande, Pradeep, Hasanzadeh, Kamal, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151794/
https://www.ncbi.nlm.nih.gov/pubmed/21837089
http://dx.doi.org/10.1107/S1600536811022070
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author Lokhande, Pradeep
Hasanzadeh, Kamal
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Lokhande, Pradeep
Hasanzadeh, Kamal
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Lokhande, Pradeep
collection PubMed
description In the title compound, C(16)H(8)ClIN(2)O(2)·C(3)H(7)NO, the fused tricyclic pyrazolo­coumarin ring and the N-phenyl ring are almost coplanar, the dihedral angle between them being 1.86 (9)°. In the crystal, these rings stack on top of each other via π–π inter­actions [centroid–centroid distances = 3.489 (2), 3.637 (2), 3.505 (2) and 3.662 (2) Å], forming infinite chains along the a axis. The chains are connected into layers parallel to ac plane through I⋯O inter­actions [3.0011 (18) Å] between pairs of symmetry-related mol­ecules. The DMF solvent mol­ecules are C—H⋯O bonded to this network.
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spelling pubmed-31517942011-08-11 8-Chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethyl­formamide monosolvate Lokhande, Pradeep Hasanzadeh, Kamal Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(8)ClIN(2)O(2)·C(3)H(7)NO, the fused tricyclic pyrazolo­coumarin ring and the N-phenyl ring are almost coplanar, the dihedral angle between them being 1.86 (9)°. In the crystal, these rings stack on top of each other via π–π inter­actions [centroid–centroid distances = 3.489 (2), 3.637 (2), 3.505 (2) and 3.662 (2) Å], forming infinite chains along the a axis. The chains are connected into layers parallel to ac plane through I⋯O inter­actions [3.0011 (18) Å] between pairs of symmetry-related mol­ecules. The DMF solvent mol­ecules are C—H⋯O bonded to this network. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151794/ /pubmed/21837089 http://dx.doi.org/10.1107/S1600536811022070 Text en © Lokhande et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lokhande, Pradeep
Hasanzadeh, Kamal
Khaledi, Hamid
Mohd Ali, Hapipah
8-Chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethyl­formamide monosolvate
title 8-Chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethyl­formamide monosolvate
title_full 8-Chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethyl­formamide monosolvate
title_fullStr 8-Chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethyl­formamide monosolvate
title_full_unstemmed 8-Chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethyl­formamide monosolvate
title_short 8-Chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2H)-one N,N-dimethyl­formamide monosolvate
title_sort 8-chloro-6-iodo-2-phenyl­chromeno[4,3-c]pyrazol-4(2h)-one n,n-dimethyl­formamide monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151794/
https://www.ncbi.nlm.nih.gov/pubmed/21837089
http://dx.doi.org/10.1107/S1600536811022070
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AT khaledihamid 8chloro6iodo2phenylchromeno43cpyrazol42honenndimethylformamidemonosolvate
AT mohdalihapipah 8chloro6iodo2phenylchromeno43cpyrazol42honenndimethylformamidemonosolvate

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