(15-Crown-5-κ(5) O)[S-(E)-1,2-dichloro­vinyl thio­sulfato-κO]sodium

In the title complex, [Na(C(2)HCl(2)O(3)S(2))(C(10)H(20)O(5))], there are two independent complex units in the asymmetric unit, one of which has a 55:45% disorder in the 15-crown-5 component. The coordination sphere about the Na atom in each complex unit comprises five bonds to O atoms of the crown...

Descripción completa

Detalles Bibliográficos
Autores principales: Sun, Dong-Qing, Yang, Jing-Kui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151796/
https://www.ncbi.nlm.nih.gov/pubmed/21836918
http://dx.doi.org/10.1107/S1600536811022252
_version_ 1782209657776898048
author Sun, Dong-Qing
Yang, Jing-Kui
author_facet Sun, Dong-Qing
Yang, Jing-Kui
author_sort Sun, Dong-Qing
collection PubMed
description In the title complex, [Na(C(2)HCl(2)O(3)S(2))(C(10)H(20)O(5))], there are two independent complex units in the asymmetric unit, one of which has a 55:45% disorder in the 15-crown-5 component. The coordination sphere about the Na atom in each complex unit comprises five bonds to O atoms of the crown ether [Na—O = 2.390 (7)–2.466 (6) Å] and one to a thio­sulfate O atom [Na—O = 2.305 (4) and 2.447 (3) Å].
format Online
Article
Text
id pubmed-3151796
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31517962011-08-11 (15-Crown-5-κ(5) O)[S-(E)-1,2-dichloro­vinyl thio­sulfato-κO]sodium Sun, Dong-Qing Yang, Jing-Kui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Na(C(2)HCl(2)O(3)S(2))(C(10)H(20)O(5))], there are two independent complex units in the asymmetric unit, one of which has a 55:45% disorder in the 15-crown-5 component. The coordination sphere about the Na atom in each complex unit comprises five bonds to O atoms of the crown ether [Na—O = 2.390 (7)–2.466 (6) Å] and one to a thio­sulfate O atom [Na—O = 2.305 (4) and 2.447 (3) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151796/ /pubmed/21836918 http://dx.doi.org/10.1107/S1600536811022252 Text en © Sun and Yang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Dong-Qing
Yang, Jing-Kui
(15-Crown-5-κ(5) O)[S-(E)-1,2-dichloro­vinyl thio­sulfato-κO]sodium
title (15-Crown-5-κ(5) O)[S-(E)-1,2-dichloro­vinyl thio­sulfato-κO]sodium
title_full (15-Crown-5-κ(5) O)[S-(E)-1,2-dichloro­vinyl thio­sulfato-κO]sodium
title_fullStr (15-Crown-5-κ(5) O)[S-(E)-1,2-dichloro­vinyl thio­sulfato-κO]sodium
title_full_unstemmed (15-Crown-5-κ(5) O)[S-(E)-1,2-dichloro­vinyl thio­sulfato-κO]sodium
title_short (15-Crown-5-κ(5) O)[S-(E)-1,2-dichloro­vinyl thio­sulfato-κO]sodium
title_sort (15-crown-5-κ(5) o)[s-(e)-1,2-dichloro­vinyl thio­sulfato-κo]sodium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151796/
https://www.ncbi.nlm.nih.gov/pubmed/21836918
http://dx.doi.org/10.1107/S1600536811022252
work_keys_str_mv AT sundongqing 15crown5k5ose12dichlorovinylthiosulfatokosodium
AT yangjingkui 15crown5k5ose12dichlorovinylthiosulfatokosodium

Ejemplares similares