(E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate

In the hydrazone mol­ecule of the title compound, C(15)H(12)ClN(3)O(4)·H(2)O, the two benzene rings form a dihedral angle of 3.6 (1)°. In the crystal structure, the solvent water mol­ecules are involved in the formation of inter­molecular N—H⋯O and O—H⋯N hydrogen bonds, which link the mol­ecules int...

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Detalles Bibliográficos
Autores principales: Liu, Shi-Yong, Wang, Xiao-Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151800/
https://www.ncbi.nlm.nih.gov/pubmed/21837031
http://dx.doi.org/10.1107/S1600536811020769
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author Liu, Shi-Yong
Wang, Xiao-Ling
author_facet Liu, Shi-Yong
Wang, Xiao-Ling
author_sort Liu, Shi-Yong
collection PubMed
description In the hydrazone mol­ecule of the title compound, C(15)H(12)ClN(3)O(4)·H(2)O, the two benzene rings form a dihedral angle of 3.6 (1)°. In the crystal structure, the solvent water mol­ecules are involved in the formation of inter­molecular N—H⋯O and O—H⋯N hydrogen bonds, which link the mol­ecules into double ribbons extending along the b axis. Inter­molecular π–π inter­actions between the aromatic rings [centroid–centroid distances = 3.712 (3) and 3.672 (3) Å] link these ribbons further into layers parallel to the ab plane.
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spelling pubmed-31518002011-08-11 (E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate Liu, Shi-Yong Wang, Xiao-Ling Acta Crystallogr Sect E Struct Rep Online Organic Papers In the hydrazone mol­ecule of the title compound, C(15)H(12)ClN(3)O(4)·H(2)O, the two benzene rings form a dihedral angle of 3.6 (1)°. In the crystal structure, the solvent water mol­ecules are involved in the formation of inter­molecular N—H⋯O and O—H⋯N hydrogen bonds, which link the mol­ecules into double ribbons extending along the b axis. Inter­molecular π–π inter­actions between the aromatic rings [centroid–centroid distances = 3.712 (3) and 3.672 (3) Å] link these ribbons further into layers parallel to the ab plane. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151800/ /pubmed/21837031 http://dx.doi.org/10.1107/S1600536811020769 Text en © Liu and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Shi-Yong
Wang, Xiao-Ling
(E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate
title (E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate
title_full (E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate
title_fullStr (E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate
title_full_unstemmed (E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate
title_short (E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate
title_sort (e)-n′-(2-chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151800/
https://www.ncbi.nlm.nih.gov/pubmed/21837031
http://dx.doi.org/10.1107/S1600536811020769
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