Tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)niobium(V)]

In the title dinuclear Nb(V) compound, [Nb(2)(C(44)H(28)N(4))(2)O(3)], each Nb atom is seven-coordinated with three bridging O atoms and four N atoms from a chelating tetra­phenyl­porphyrinate anion. The Nb—O bond lengths range from 1.757 (6) to 2.331 (6) Å, and the average (niobium–pyrrole N atom)...

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Autores principales: Soury, Raoudha, Belkhiria, Mohamed Salah, Daran, Jean-Claude, Nasri, Habib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151801/
https://www.ncbi.nlm.nih.gov/pubmed/21836860
http://dx.doi.org/10.1107/S1600536811020538
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author Soury, Raoudha
Belkhiria, Mohamed Salah
Daran, Jean-Claude
Nasri, Habib
author_facet Soury, Raoudha
Belkhiria, Mohamed Salah
Daran, Jean-Claude
Nasri, Habib
author_sort Soury, Raoudha
collection PubMed
description In the title dinuclear Nb(V) compound, [Nb(2)(C(44)H(28)N(4))(2)O(3)], each Nb atom is seven-coordinated with three bridging O atoms and four N atoms from a chelating tetra­phenyl­porphyrinate anion. The Nb—O bond lengths range from 1.757 (6) to 2.331 (6) Å, and the average (niobium–pyrrole N atom) distance is 2.239 Å. In the dinuclear mol­ecule, the Nb⋯Nb separation is 2.8200 (8) Å, and the dihedral angle between the two porphyrinate mean planes is 5.4 (1)°. Weak inter­molecular C—H⋯π inter­actions are present in the crystal structure.
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spelling pubmed-31518012011-08-11 Tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)niobium(V)] Soury, Raoudha Belkhiria, Mohamed Salah Daran, Jean-Claude Nasri, Habib Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear Nb(V) compound, [Nb(2)(C(44)H(28)N(4))(2)O(3)], each Nb atom is seven-coordinated with three bridging O atoms and four N atoms from a chelating tetra­phenyl­porphyrinate anion. The Nb—O bond lengths range from 1.757 (6) to 2.331 (6) Å, and the average (niobium–pyrrole N atom) distance is 2.239 Å. In the dinuclear mol­ecule, the Nb⋯Nb separation is 2.8200 (8) Å, and the dihedral angle between the two porphyrinate mean planes is 5.4 (1)°. Weak inter­molecular C—H⋯π inter­actions are present in the crystal structure. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151801/ /pubmed/21836860 http://dx.doi.org/10.1107/S1600536811020538 Text en © Soury et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Soury, Raoudha
Belkhiria, Mohamed Salah
Daran, Jean-Claude
Nasri, Habib
Tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)niobium(V)]
title Tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)niobium(V)]
title_full Tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)niobium(V)]
title_fullStr Tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)niobium(V)]
title_full_unstemmed Tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)niobium(V)]
title_short Tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)niobium(V)]
title_sort tri-μ-oxido-bis­[(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)niobium(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151801/
https://www.ncbi.nlm.nih.gov/pubmed/21836860
http://dx.doi.org/10.1107/S1600536811020538
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