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Dichlorido(2-{[3-(morpholin-4-ium-4-yl)propyl]iminomethyl}phenolate)zinc
In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral co...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151802/ https://www.ncbi.nlm.nih.gov/pubmed/21836916 http://dx.doi.org/10.1107/S1600536811022021 |
Sumario: | In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination environment. In the crystal, a pair of N—H⋯O hydrogen bonds connect the molecules into a centrosymmetric dimer. C—H⋯O, C—H⋯Cl and C—H⋯π interactions are also observed. |
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