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Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc

In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetra­hedral co...

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Detalles Bibliográficos
Autores principales: Ikmal Hisham, Nurul Azimah, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151802/
https://www.ncbi.nlm.nih.gov/pubmed/21836916
http://dx.doi.org/10.1107/S1600536811022021
Descripción
Sumario:In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetra­hedral coordination environment. In the crystal, a pair of N—H⋯O hydrogen bonds connect the mol­ecules into a centrosymmetric dimer. C—H⋯O, C—H⋯Cl and C—H⋯π inter­actions are also observed.