Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc

In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetra­hedral co...

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Autores principales: Ikmal Hisham, Nurul Azimah, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151802/
https://www.ncbi.nlm.nih.gov/pubmed/21836916
http://dx.doi.org/10.1107/S1600536811022021
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author Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Ikmal Hisham, Nurul Azimah
collection PubMed
description In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetra­hedral coordination environment. In the crystal, a pair of N—H⋯O hydrogen bonds connect the mol­ecules into a centrosymmetric dimer. C—H⋯O, C—H⋯Cl and C—H⋯π inter­actions are also observed.
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spelling pubmed-31518022011-08-11 Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetra­hedral coordination environment. In the crystal, a pair of N—H⋯O hydrogen bonds connect the mol­ecules into a centrosymmetric dimer. C—H⋯O, C—H⋯Cl and C—H⋯π inter­actions are also observed. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151802/ /pubmed/21836916 http://dx.doi.org/10.1107/S1600536811022021 Text en © Ikmal Hisham et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc
title Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc
title_full Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc
title_fullStr Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc
title_full_unstemmed Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc
title_short Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc
title_sort dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop­yl]imino­meth­yl}phenolate)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151802/
https://www.ncbi.nlm.nih.gov/pubmed/21836916
http://dx.doi.org/10.1107/S1600536811022021
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