Bis[2-(1H-imidazol-2-yl-κN (3))-1H-imidazol-3-ium]silver(I) trinitrate

The synthesis of the title salt, [Ag(C(6)H(7)N(4))(2)](NO(3))(3), was carried out employing a 1:2 molar ratio of 2,2′-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N—Ag—N = 177.01...

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Autores principales: Finch, Shelonda R., Harper, Johnathan P., Choudhury, Amitava, Sinn, Ekkehard, Collier, Harvest L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151805/
https://www.ncbi.nlm.nih.gov/pubmed/21836895
http://dx.doi.org/10.1107/S1600536811021799
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author Finch, Shelonda R.
Harper, Johnathan P.
Choudhury, Amitava
Sinn, Ekkehard
Collier, Harvest L.
author_facet Finch, Shelonda R.
Harper, Johnathan P.
Choudhury, Amitava
Sinn, Ekkehard
Collier, Harvest L.
author_sort Finch, Shelonda R.
collection PubMed
description The synthesis of the title salt, [Ag(C(6)H(7)N(4))(2)](NO(3))(3), was carried out employing a 1:2 molar ratio of 2,2′-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N—Ag—N = 177.01 (17)°]. The crystal structure displays N—H⋯O and C—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-31518052011-08-11 Bis[2-(1H-imidazol-2-yl-κN (3))-1H-imidazol-3-ium]silver(I) trinitrate Finch, Shelonda R. Harper, Johnathan P. Choudhury, Amitava Sinn, Ekkehard Collier, Harvest L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The synthesis of the title salt, [Ag(C(6)H(7)N(4))(2)](NO(3))(3), was carried out employing a 1:2 molar ratio of 2,2′-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N—Ag—N = 177.01 (17)°]. The crystal structure displays N—H⋯O and C—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151805/ /pubmed/21836895 http://dx.doi.org/10.1107/S1600536811021799 Text en © Finch et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Finch, Shelonda R.
Harper, Johnathan P.
Choudhury, Amitava
Sinn, Ekkehard
Collier, Harvest L.
Bis[2-(1H-imidazol-2-yl-κN (3))-1H-imidazol-3-ium]silver(I) trinitrate
title Bis[2-(1H-imidazol-2-yl-κN (3))-1H-imidazol-3-ium]silver(I) trinitrate
title_full Bis[2-(1H-imidazol-2-yl-κN (3))-1H-imidazol-3-ium]silver(I) trinitrate
title_fullStr Bis[2-(1H-imidazol-2-yl-κN (3))-1H-imidazol-3-ium]silver(I) trinitrate
title_full_unstemmed Bis[2-(1H-imidazol-2-yl-κN (3))-1H-imidazol-3-ium]silver(I) trinitrate
title_short Bis[2-(1H-imidazol-2-yl-κN (3))-1H-imidazol-3-ium]silver(I) trinitrate
title_sort bis[2-(1h-imidazol-2-yl-κn (3))-1h-imidazol-3-ium]silver(i) trinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151805/
https://www.ncbi.nlm.nih.gov/pubmed/21836895
http://dx.doi.org/10.1107/S1600536811021799
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