6-Methyl-2,3,4,9-tetra­hydro-1H-carbazole-1-thione

In the title mol­ecule, C(13)H(13)NS, the dihedral angle between the benzene ring and the fused pyrrole ring is 0.71 (8)° and the cyclo­hexene ring is in an envelope form. The (CH(2))(3) atoms of the cyclo­hexene ring are disordered over two positions; the site-occupancy factor for the major compone...

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Autores principales: Archana, R., Prabakaran, K., Rajendra Prasad, K. J., Thiruvalluvar, A., Butcher, R. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151814/
https://www.ncbi.nlm.nih.gov/pubmed/21837047
http://dx.doi.org/10.1107/S1600536811019246
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author Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
author_facet Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
author_sort Archana, R.
collection PubMed
description In the title mol­ecule, C(13)H(13)NS, the dihedral angle between the benzene ring and the fused pyrrole ring is 0.71 (8)° and the cyclo­hexene ring is in an envelope form. The (CH(2))(3) atoms of the cyclo­hexene ring are disordered over two positions; the site-occupancy factor for the major component refined to 0.862 (4). In the crystal, inter­molecular N—H⋯S hydrogen bonds lead to the formation of centrosymmetric aggregates via an R (2) (2)(10) ring.
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spelling pubmed-31518142011-08-11 6-Methyl-2,3,4,9-tetra­hydro-1H-carbazole-1-thione Archana, R. Prabakaran, K. Rajendra Prasad, K. J. Thiruvalluvar, A. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(13)H(13)NS, the dihedral angle between the benzene ring and the fused pyrrole ring is 0.71 (8)° and the cyclo­hexene ring is in an envelope form. The (CH(2))(3) atoms of the cyclo­hexene ring are disordered over two positions; the site-occupancy factor for the major component refined to 0.862 (4). In the crystal, inter­molecular N—H⋯S hydrogen bonds lead to the formation of centrosymmetric aggregates via an R (2) (2)(10) ring. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151814/ /pubmed/21837047 http://dx.doi.org/10.1107/S1600536811019246 Text en © Archana et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
6-Methyl-2,3,4,9-tetra­hydro-1H-carbazole-1-thione
title 6-Methyl-2,3,4,9-tetra­hydro-1H-carbazole-1-thione
title_full 6-Methyl-2,3,4,9-tetra­hydro-1H-carbazole-1-thione
title_fullStr 6-Methyl-2,3,4,9-tetra­hydro-1H-carbazole-1-thione
title_full_unstemmed 6-Methyl-2,3,4,9-tetra­hydro-1H-carbazole-1-thione
title_short 6-Methyl-2,3,4,9-tetra­hydro-1H-carbazole-1-thione
title_sort 6-methyl-2,3,4,9-tetra­hydro-1h-carbazole-1-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151814/
https://www.ncbi.nlm.nih.gov/pubmed/21837047
http://dx.doi.org/10.1107/S1600536811019246
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AT thiruvalluvara 6methyl2349tetrahydro1hcarbazole1thione
AT butcherrj 6methyl2349tetrahydro1hcarbazole1thione

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