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Bis(2-ethyl-1H-imidazole-κN (3))bis(nitrito-κ(2) O,O′)copper(II) dihydrate
In the title compound, [Cu(NO(2))(2)(C(5)H(8)N(2))]·2H(2)O, the Cu(2+) ion exhibits site symmetry 2 and is hexacoordinated by four O atoms from two nitrite ions and two N atoms from two 2-ethyl-1H-imidazole molecules. A free water molecule assists in forming a three-dimensional network holding tog...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151815/ https://www.ncbi.nlm.nih.gov/pubmed/21836921 http://dx.doi.org/10.1107/S1600536811022367 |
| _version_ | 1782209662131634176 |
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| author | Zhu, Run-Qiang |
| author_facet | Zhu, Run-Qiang |
| author_sort | Zhu, Run-Qiang |
| collection | PubMed |
| description | In the title compound, [Cu(NO(2))(2)(C(5)H(8)N(2))]·2H(2)O, the Cu(2+) ion exhibits site symmetry 2 and is hexacoordinated by four O atoms from two nitrite ions and two N atoms from two 2-ethyl-1H-imidazole molecules. A free water molecule assists in forming a three-dimensional network holding together the complexes via O—H⋯N, O—H⋯O and N—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3151815 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31518152011-08-11 Bis(2-ethyl-1H-imidazole-κN (3))bis(nitrito-κ(2) O,O′)copper(II) dihydrate Zhu, Run-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NO(2))(2)(C(5)H(8)N(2))]·2H(2)O, the Cu(2+) ion exhibits site symmetry 2 and is hexacoordinated by four O atoms from two nitrite ions and two N atoms from two 2-ethyl-1H-imidazole molecules. A free water molecule assists in forming a three-dimensional network holding together the complexes via O—H⋯N, O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151815/ /pubmed/21836921 http://dx.doi.org/10.1107/S1600536811022367 Text en © Run-Qiang Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhu, Run-Qiang Bis(2-ethyl-1H-imidazole-κN (3))bis(nitrito-κ(2) O,O′)copper(II) dihydrate |
| title | Bis(2-ethyl-1H-imidazole-κN
(3))bis(nitrito-κ(2)
O,O′)copper(II) dihydrate |
| title_full | Bis(2-ethyl-1H-imidazole-κN
(3))bis(nitrito-κ(2)
O,O′)copper(II) dihydrate |
| title_fullStr | Bis(2-ethyl-1H-imidazole-κN
(3))bis(nitrito-κ(2)
O,O′)copper(II) dihydrate |
| title_full_unstemmed | Bis(2-ethyl-1H-imidazole-κN
(3))bis(nitrito-κ(2)
O,O′)copper(II) dihydrate |
| title_short | Bis(2-ethyl-1H-imidazole-κN
(3))bis(nitrito-κ(2)
O,O′)copper(II) dihydrate |
| title_sort | bis(2-ethyl-1h-imidazole-κn
(3))bis(nitrito-κ(2)
o,o′)copper(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151815/ https://www.ncbi.nlm.nih.gov/pubmed/21836921 http://dx.doi.org/10.1107/S1600536811022367 |
| work_keys_str_mv | AT zhurunqiang bis2ethyl1himidazolekn3bisnitritok2oocopperiidihydrate |