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{N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)copper(II)

The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol­ecules. In each mol­ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N′,N"-tridentate Schif...

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Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151817/
https://www.ncbi.nlm.nih.gov/pubmed/21836914
http://dx.doi.org/10.1107/S1600536811022057
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author Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol­ecules. In each mol­ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N′,N"-tridentate Schiff base and one N-bound thio­cyanate ligand. The second N-donor thio­cyanate group, located at the apical site, completes the coordination environment. In the crystal, inter­molecular C—H⋯S and C—H⋯N hydrogen bonds link adjacent mol­ecules into infinite layers parallel to the ac plane. Intra­molecular C—H⋯N inter­actions are also observed.
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spelling pubmed-31518172011-08-11 {N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)copper(II) Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol­ecules. In each mol­ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N′,N"-tridentate Schiff base and one N-bound thio­cyanate ligand. The second N-donor thio­cyanate group, located at the apical site, completes the coordination environment. In the crystal, inter­molecular C—H⋯S and C—H⋯N hydrogen bonds link adjacent mol­ecules into infinite layers parallel to the ac plane. Intra­molecular C—H⋯N inter­actions are also observed. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151817/ /pubmed/21836914 http://dx.doi.org/10.1107/S1600536811022057 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
{N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)copper(II)
title {N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)copper(II)
title_full {N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)copper(II)
title_fullStr {N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)copper(II)
title_full_unstemmed {N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)copper(II)
title_short {N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)copper(II)
title_sort {n,n-dimethyl-n′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) n,n′,n′′}bis­(thio­cyanato-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151817/
https://www.ncbi.nlm.nih.gov/pubmed/21836914
http://dx.doi.org/10.1107/S1600536811022057
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