Cargando…
{N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)copper(II)
The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent molecules. In each molecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N′,N"-tridentate Schif...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151817/ https://www.ncbi.nlm.nih.gov/pubmed/21836914 http://dx.doi.org/10.1107/S1600536811022057 |
_version_ | 1782209662575181824 |
---|---|
author | Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
author_facet | Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
author_sort | Suleiman Gwaram, Nura |
collection | PubMed |
description | The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent molecules. In each molecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N′,N"-tridentate Schiff base and one N-bound thiocyanate ligand. The second N-donor thiocyanate group, located at the apical site, completes the coordination environment. In the crystal, intermolecular C—H⋯S and C—H⋯N hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. Intramolecular C—H⋯N interactions are also observed. |
format | Online Article Text |
id | pubmed-3151817 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31518172011-08-11 {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)copper(II) Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent molecules. In each molecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N′,N"-tridentate Schiff base and one N-bound thiocyanate ligand. The second N-donor thiocyanate group, located at the apical site, completes the coordination environment. In the crystal, intermolecular C—H⋯S and C—H⋯N hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. Intramolecular C—H⋯N interactions are also observed. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151817/ /pubmed/21836914 http://dx.doi.org/10.1107/S1600536811022057 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)copper(II) |
title | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
title_full | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
title_fullStr | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
title_full_unstemmed | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
title_short | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)copper(II) |
title_sort | {n,n-dimethyl-n′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
n,n′,n′′}bis(thiocyanato-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151817/ https://www.ncbi.nlm.nih.gov/pubmed/21836914 http://dx.doi.org/10.1107/S1600536811022057 |
work_keys_str_mv | AT suleimangwaramnura nndimethyln12pyridylethylideneethane12diaminek3nnnbisthiocyanatokncopperii AT khaledihamid nndimethyln12pyridylethylideneethane12diaminek3nnnbisthiocyanatokncopperii AT mohdalihapipah nndimethyln12pyridylethylideneethane12diaminek3nnnbisthiocyanatokncopperii |