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Poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)]
In the crystal structure of the title two-dimensional network, [HgCl(2)(C(11)H(10)N(2)O)](n), the asymmetric unit consists of HgCl(2) dumbbells and one molecule of the quinazoline unit. Pseudo-octahedrally coordinated Hg(II) cations are chloride-bridged via a crystallographic inversion centre lead...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151818/ https://www.ncbi.nlm.nih.gov/pubmed/21836934 http://dx.doi.org/10.1107/S1600536811022471 |
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author | Turgunov, Kambarali K. Wang, Yutian Englert, Ulli Shakhidoyatov, Khusnutdin M. |
author_facet | Turgunov, Kambarali K. Wang, Yutian Englert, Ulli Shakhidoyatov, Khusnutdin M. |
author_sort | Turgunov, Kambarali K. |
collection | PubMed |
description | In the crystal structure of the title two-dimensional network, [HgCl(2)(C(11)H(10)N(2)O)](n), the asymmetric unit consists of HgCl(2) dumbbells and one molecule of the quinazoline unit. Pseudo-octahedrally coordinated Hg(II) cations are chloride-bridged via a crystallographic inversion centre leading to different Hg—Cl bonds (short and long) and linked by other Cl atoms via translation along the a axis. The quinazoline ligands connect the Hg—Cl—Hg—Cl chains by N and O atoms along the b axis, forming the two-dimensional network structure. The crystal structure is stabilized by weak non-classical C—H⋯Cl hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid distances = 3.942 (4) and 3.621 (4) Å]. |
format | Online Article Text |
id | pubmed-3151818 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31518182011-08-11 Poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)] Turgunov, Kambarali K. Wang, Yutian Englert, Ulli Shakhidoyatov, Khusnutdin M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title two-dimensional network, [HgCl(2)(C(11)H(10)N(2)O)](n), the asymmetric unit consists of HgCl(2) dumbbells and one molecule of the quinazoline unit. Pseudo-octahedrally coordinated Hg(II) cations are chloride-bridged via a crystallographic inversion centre leading to different Hg—Cl bonds (short and long) and linked by other Cl atoms via translation along the a axis. The quinazoline ligands connect the Hg—Cl—Hg—Cl chains by N and O atoms along the b axis, forming the two-dimensional network structure. The crystal structure is stabilized by weak non-classical C—H⋯Cl hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid distances = 3.942 (4) and 3.621 (4) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151818/ /pubmed/21836934 http://dx.doi.org/10.1107/S1600536811022471 Text en © Turgunov et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Turgunov, Kambarali K. Wang, Yutian Englert, Ulli Shakhidoyatov, Khusnutdin M. Poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)] |
title | Poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2)
N:O)-mercury(II)] |
title_full | Poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2)
N:O)-mercury(II)] |
title_fullStr | Poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2)
N:O)-mercury(II)] |
title_full_unstemmed | Poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2)
N:O)-mercury(II)] |
title_short | Poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2)
N:O)-mercury(II)] |
title_sort | poly[di-μ-chlorido-μ-(1,2,3,9-tetrahydropyrrolo[2,1-b]quinazolin-9-one-κ(2)
n:o)-mercury(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151818/ https://www.ncbi.nlm.nih.gov/pubmed/21836934 http://dx.doi.org/10.1107/S1600536811022471 |
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