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Poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)]

In the crystal structure of the title two-dimensional network, [HgCl(2)(C(11)H(10)N(2)O)](n), the asymmetric unit consists of HgCl(2) dumbbells and one mol­ecule of the quinazoline unit. Pseudo-octa­hedrally coordinated Hg(II) cations are chloride-bridged via a crystallographic inversion centre lead...

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Autores principales: Turgunov, Kambarali K., Wang, Yutian, Englert, Ulli, Shakhidoyatov, Khusnutdin M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151818/
https://www.ncbi.nlm.nih.gov/pubmed/21836934
http://dx.doi.org/10.1107/S1600536811022471
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author Turgunov, Kambarali K.
Wang, Yutian
Englert, Ulli
Shakhidoyatov, Khusnutdin M.
author_facet Turgunov, Kambarali K.
Wang, Yutian
Englert, Ulli
Shakhidoyatov, Khusnutdin M.
author_sort Turgunov, Kambarali K.
collection PubMed
description In the crystal structure of the title two-dimensional network, [HgCl(2)(C(11)H(10)N(2)O)](n), the asymmetric unit consists of HgCl(2) dumbbells and one mol­ecule of the quinazoline unit. Pseudo-octa­hedrally coordinated Hg(II) cations are chloride-bridged via a crystallographic inversion centre leading to different Hg—Cl bonds (short and long) and linked by other Cl atoms via translation along the a axis. The quinazoline ligands connect the Hg—Cl—Hg—Cl chains by N and O atoms along the b axis, forming the two-dimensional network structure. The crystal structure is stabilized by weak non-classical C—H⋯Cl hydrogen bonds and aromatic π–π stacking inter­actions [centroid–centroid distances = 3.942 (4) and 3.621 (4) Å].
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spelling pubmed-31518182011-08-11 Poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)] Turgunov, Kambarali K. Wang, Yutian Englert, Ulli Shakhidoyatov, Khusnutdin M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title two-dimensional network, [HgCl(2)(C(11)H(10)N(2)O)](n), the asymmetric unit consists of HgCl(2) dumbbells and one mol­ecule of the quinazoline unit. Pseudo-octa­hedrally coordinated Hg(II) cations are chloride-bridged via a crystallographic inversion centre leading to different Hg—Cl bonds (short and long) and linked by other Cl atoms via translation along the a axis. The quinazoline ligands connect the Hg—Cl—Hg—Cl chains by N and O atoms along the b axis, forming the two-dimensional network structure. The crystal structure is stabilized by weak non-classical C—H⋯Cl hydrogen bonds and aromatic π–π stacking inter­actions [centroid–centroid distances = 3.942 (4) and 3.621 (4) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151818/ /pubmed/21836934 http://dx.doi.org/10.1107/S1600536811022471 Text en © Turgunov et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Turgunov, Kambarali K.
Wang, Yutian
Englert, Ulli
Shakhidoyatov, Khusnutdin M.
Poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)]
title Poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)]
title_full Poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)]
title_fullStr Poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)]
title_full_unstemmed Poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)]
title_short Poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) N:O)-mercury(II)]
title_sort poly[di-μ-chlorido-μ-(1,2,3,9-tetra­hydro­pyrrolo­[2,1-b]quinazolin-9-one-κ(2) n:o)-mercury(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151818/
https://www.ncbi.nlm.nih.gov/pubmed/21836934
http://dx.doi.org/10.1107/S1600536811022471
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