Cargando…
catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ(2) N,N′)manganese(II)]-μ-formato-κ(2) O:O′] monohydrate]
The title compound, {[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), consists of polymeric chains of the complex [Mn(HCOO)(2)(phen)(H(2)O)](∞) (phen is 1,10-phenanthroline) with solvent water molecules. The chains contain six-coordinate Mn(II) ions bridged by formate anions. They are further extende...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151819/ https://www.ncbi.nlm.nih.gov/pubmed/21836883 http://dx.doi.org/10.1107/S1600536811020575 |
_version_ | 1782209663017680896 |
---|---|
author | Xu, Wei |
author_facet | Xu, Wei |
author_sort | Xu, Wei |
collection | PubMed |
description | The title compound, {[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), consists of polymeric chains of the complex [Mn(HCOO)(2)(phen)(H(2)O)](∞) (phen is 1,10-phenanthroline) with solvent water molecules. The chains contain six-coordinate Mn(II) ions bridged by formate anions. They are further extended into a three-dimensional network via O—H⋯O hydrogen-bonding interactions and interchain π–π stacking interactions, with a centroid–centroid distance of 3.679 (4) Å. |
format | Online Article Text |
id | pubmed-3151819 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31518192011-08-11 catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ(2) N,N′)manganese(II)]-μ-formato-κ(2) O:O′] monohydrate] Xu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), consists of polymeric chains of the complex [Mn(HCOO)(2)(phen)(H(2)O)](∞) (phen is 1,10-phenanthroline) with solvent water molecules. The chains contain six-coordinate Mn(II) ions bridged by formate anions. They are further extended into a three-dimensional network via O—H⋯O hydrogen-bonding interactions and interchain π–π stacking interactions, with a centroid–centroid distance of 3.679 (4) Å. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151819/ /pubmed/21836883 http://dx.doi.org/10.1107/S1600536811020575 Text en © Wei Xu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Wei catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ(2) N,N′)manganese(II)]-μ-formato-κ(2) O:O′] monohydrate] |
title |
catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-μ-formato-κ(2)
O:O′] monohydrate] |
title_full |
catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-μ-formato-κ(2)
O:O′] monohydrate] |
title_fullStr |
catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-μ-formato-κ(2)
O:O′] monohydrate] |
title_full_unstemmed |
catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-μ-formato-κ(2)
O:O′] monohydrate] |
title_short |
catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ(2)
N,N′)manganese(II)]-μ-formato-κ(2)
O:O′] monohydrate] |
title_sort | catena-poly[[[aqua(formato-κo)(1,10-phenanthroline-κ(2)
n,n′)manganese(ii)]-μ-formato-κ(2)
o:o′] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151819/ https://www.ncbi.nlm.nih.gov/pubmed/21836883 http://dx.doi.org/10.1107/S1600536811020575 |
work_keys_str_mv | AT xuwei catenapolyaquaformatoko110phenanthrolinek2nnmanganeseiimformatok2oomonohydrate |