1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole

The title compound, C(26)H(23)BrN(6), has been synthesized as a potential ligand for the construction of metal–organic frameworks. The three benzimidazolyl groups present three potential coordination nodes. The dihedral angles between the benzimidazole ring systems are 74.03 (10), 66.49 (9) and 74.0...

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Detalles Bibliográficos
Autores principales: Wei, Tai-Bao, Lu, Yan-Yun, Cao, Cheng, Yao, Hong, Zhang, You-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151820/
https://www.ncbi.nlm.nih.gov/pubmed/21837200
http://dx.doi.org/10.1107/S1600536811023464
Descripción
Sumario:The title compound, C(26)H(23)BrN(6), has been synthesized as a potential ligand for the construction of metal–organic frameworks. The three benzimidazolyl groups present three potential coordination nodes. The dihedral angles between the benzimidazole ring systems are 74.03 (10), 66.49 (9) and 74.09 (9)°. The structure contains large voids, which contain highly disordered solvent mol­ecules that may be CH(3)CH(2)OH. Since the solvent mol­ecules could not be located, the PLATON/SQUEEZE procedure [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used.

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